Development and characterisation of photoelectrochemical MIS structures with RuO2/TiO2 gate stacs for water oxidation

This paper is dedicated to preparation and analysis of metal insulator semiconductor (MIS) photoanode with a metal organic chemical vapor deposited RuO layer and TiO protection layer for photoelectrochemical water splitting. It is shown that utilization of TiO layers of 2, 4, and 6 nm thickness pres...

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Veröffentlicht in:Journal of Electrical Engineering 2021-06, Vol.72 (3), p.203-207
Hauptverfasser: Mikolášek, Miroslav, Fröhlich, Karol, Hušeková, Kristína, Ondrejka, Peter, Chymo, Filip, Kemény, Martin, Hotovy, Ivan, Harmatha, Ladislav
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container_end_page 207
container_issue 3
container_start_page 203
container_title Journal of Electrical Engineering
container_volume 72
creator Mikolášek, Miroslav
Fröhlich, Karol
Hušeková, Kristína
Ondrejka, Peter
Chymo, Filip
Kemény, Martin
Hotovy, Ivan
Harmatha, Ladislav
description This paper is dedicated to preparation and analysis of metal insulator semiconductor (MIS) photoanode with a metal organic chemical vapor deposited RuO layer and TiO protection layer for photoelectrochemical water splitting. It is shown that utilization of TiO layers of 2, 4, and 6 nm thickness preserve the catalytic activity of underlying RuO . The origin of increased overpotential and decreased photovoltage of the photoanode upon the increase of TiO layer thickness is discussed in the paper. Results revealed that utilization of TiO layer in the MIS concept is suitable for photoelectrochemical water oxidation applications.
doi_str_mv 10.2478/jee-2021-0028
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source Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; Walter De Gruyter: Open Access Journals
subjects Catalytic activity
Chemical vapor deposition
MIS
MIS (semiconductors)
Organic chemicals
Organic chemistry
Oxidation
RuO
Ruthenium oxide
Thickness
TiO
Titanium dioxide
water oxidation
Water splitting
title Development and characterisation of photoelectrochemical MIS structures with RuO2/TiO2 gate stacs for water oxidation
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