Superior energy storage properties in (1−x)(0.65Bi0.5Na0.5TiO3-0.35Bi0.2Sr0.7TiO3)-xCaZrO3 ceramics with excellent temperature stability

•Large recoverable energy storage density of 2.9 J/cm3 is obtained in BNT-BST-CZ ceramic.•The ceramic shows excellent dielectric permittivity stability at 44-483 °C.•The ceramic owns a fast charge-discharge speed of 110 ns. In the 0.9(0.65Bi0.5Na0.5TiO3-0.35Bi0.2Sr0.7TiO3)-0.1CaZrO3 ceramic, superior energy storage performance and excellent dielectric stability have been achieved, along with a higher discharge rate. Our finding suggests that the ceramic has great potential applications in pulsed power systems and high-temperature capacitors. [Display omitted] Novel (1−x)(0.65Bi0.5Na0.5TiO3-0.35Bi0.2Sr0.7TiO3)-xCaZrO3 (BNT-BST-xCZ, x = 0–0.15) ceramics were manufactured through a solid phase sintering process and their structural and electrical performance have been systematically investigated. By doping CaZrO3, a higher recoverable energy storage density of 2.9 J/cm3 and energy storage efficiency of 80% at 330 kV/cm can be simultaneously obtained in BNT-BST-0.1CZ ceramic. Further analysis with the aid of finite element simulation indicates that the improvement of energy storage performance lies in the refined grain size and reduced defects, which are both conductive to improve the dielectric breakdown strength. More importantly, incorporating CaZrO3 gives slimmer hysteresis loops as well as excellent temperature (20–150 °C) and frequency (5–200 Hz) stability of energy storage properties. Moreover, a stable dielectric permittivity of in an ultra-wide range from 44 °C to 483 °C was achieved in BNT-BST-0.10CZ ceramic. Our findings suggest that the BNT-BST-0.1CZ ceramic has great potential applications in pulsed power systems and high-temperature capacitors.