A P-type mid-infrared transparent semiconductor LaSe2 film with small hole effective mass and high carrier concentration

P-type transparent conductive materials (TCMs) are urgently needed in the development of photoelectric devices. In particular, the P-type TCMs that can be applied in the mid-infrared range are even rarer due to the conflict between the transparent range and the conductivity of materials. In this wor...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Applied physics letters 2021-06, Vol.118 (26)
Hauptverfasser: Gao, Gang, Tong, Lijia, Yang, Lei, Sun, Chunqiang, Xu, Liangge, Xia, Fei, Geng, Fangjuan, Xue, Jingjing, Gong, Hao, Zhu, Jiaqi
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:P-type transparent conductive materials (TCMs) are urgently needed in the development of photoelectric devices. In particular, the P-type TCMs that can be applied in the mid-infrared range are even rarer due to the conflict between the transparent range and the conductivity of materials. In this work, a P-type mid-infrared transparent conductive LaSe2 film is obtained by a two-step method combining the RF sputtering and a selenized annealing process. The crystal structure of the film has been confirmed by x-ray diffraction and Raman spectrum analysis. According to the Hall effect measurement results, the LaSe2 film has a higher conductivity (about 3.6 S/cm) than that of traditional P-type mid-infrared TCMs, which is attributed to its ten times higher carrier concentration (about 1019 cm−3) and a much smaller hole effective mass (about 0.34 me) compared to the conventional P-type mid-infrared TCMs. The transmittance (about 75%) is at the same level as that of the traditional P-type mid-infrared TCMs. In a sense, the LaSe2 is a promising candidate material for the development of mid-infrared photoelectric devices.
ISSN:0003-6951
1077-3118
DOI:10.1063/5.0055888