Molecular motion in organometallic crystals: photoinduced 2π/5 rotation of n -hexyltetramethylcyclopentadienyl ligand

Molecular motion in organometallic crystals: photoinduced 2π/5 rotation of n -hexyltetramethylcyclopentadienyl ligand

Crystalline-state photoreaction of a newly prepared organorhodium dithionite complex with n -hexyltetramethyl-cyclopentadienyl (Cp Hex : η 5 -C 5 Me 4 n -Hexyl) ligands was studied by single crystal X-ray diffraction experiments; 2π/5 rotation of the Cp Hex ligand is induced by the photoisomerizatio...

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Veröffentlicht in:CrystEngComm 2021-06, Vol.23 (21), p.3790-3793
Hauptverfasser: Nakai, Hidetaka, Kajiwara, Yuu, Miyata, Seiya
Format: Artikel
Sprache:eng
Schlagworte:
Chain dynamics
Crystallography
Crystals
Ligands
Molecular motion
Rotation
Single crystals
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Zusammenfassung:Crystalline-state photoreaction of a newly prepared organorhodium dithionite complex with n -hexyltetramethyl-cyclopentadienyl (Cp Hex : η 5 -C 5 Me 4 n -Hexyl) ligands was studied by single crystal X-ray diffraction experiments; 2π/5 rotation of the Cp Hex ligand is induced by the photoisomerization of the dithionite group (μ-O 2 SSO 2 ).
ISSN:1466-8033
1466-8033
DOI:10.1039/D1CE00093D