Photocatalytic Hydrogen Evolution Coupled with Production of Highly Value‐Added Organic Chemicals by a Composite Photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2

Photocatalytic water splitting coupled with the production of highly value‐added organic chemicals is of significant importance, which represents a very promising pathway for transforming green solar energy into chemical energy. Herein, we report a composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, wh...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chemistry, an Asian journal an Asian journal, 2021-06, Vol.16 (11), p.1499-1506
Hauptverfasser: Zhang, Huan‐Huan, Zhan, Guo‐Peng, Liu, Zi‐Kun, Wu, Chuan‐De
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 1506
container_issue 11
container_start_page 1499
container_title Chemistry, an Asian journal
container_volume 16
creator Zhang, Huan‐Huan
Zhan, Guo‐Peng
Liu, Zi‐Kun
Wu, Chuan‐De
description Photocatalytic water splitting coupled with the production of highly value‐added organic chemicals is of significant importance, which represents a very promising pathway for transforming green solar energy into chemical energy. Herein, we report a composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, which is highly efficient on prompting water splitting for the production of H2 in the reduction half‐reaction and selective oxidation of organic molecules for the production of highly value‐added organic chemicals in the oxidation half‐reaction under visible light irradiation. The superior photocatalytic properties of the composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2 should be ascribed to coating suspended ion catalyst (SIC), consisting of redox‐active NiII ions in the anionic pores of coordination network MIL‐53‐SO3−, on the surface of photoactive CdIn2S4, which endows photogenerated electron‐hole pairs separate more efficiently for high rate production of H2 and selective production of highly value‐added organic products, demonstrating great potential for practical applications. A composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, consisting of photoactive cadmium indium sulphide core and suspended ion catalyst MIL‐53‐SO3Ni1/2 shell, demonstrates high photocatalytic efficiency and stability in H2 evolution coupled with production of highly value‐added imines under visible light irradiation.
doi_str_mv 10.1002/asia.202100262
format Article
fullrecord <record><control><sourceid>proquest_wiley</sourceid><recordid>TN_cdi_proquest_journals_2535016185</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2535016185</sourcerecordid><originalsourceid>FETCH-LOGICAL-g2702-f688da59f7102dcea14107c7dc61feb4ad942e268e474cfa83cb2a248b74f26f3</originalsourceid><addsrcrecordid>eNpNkM9Kw0AQxoMoWKtXzwue0-5ONsnmZgjVFqotVMVb2O5uki1pNuaPJTcfwQfw6XwSUyvFy8x8wze_gc-yrgkeEYxhzGvNR4BhLzw4sQaEecSmPnk9Pc7Azq2Lut5g7AIO2MD6WmamMYI3PO8aLdC0k5VJVYEm7yZvG20KFJm2zJVEO91kaFkZ2YrfvUnQVKdZ3qEXnrfq--MzlLL3LaqUFz0qytRWC57XaN0h3mO2pal1o9C_l3WDIjkrYEVvH2bzHuE6fVktnEdNxnBpnSX9vbr660Pr-W7yFE3t-eJ-FoVzOwUfg514jEnuBolPMEihOKEE-8KXwiOJWlMuAwoKPKaoT0XCmSPWwIGytU8T8BJnaN0cuGVl3lpVN_HGtFXRv4zBdVxMPMLc3hUcXDudqy4uK73lVRcTHO8Tj_fxx8f443A1C4_K-QGMx3-V</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2535016185</pqid></control><display><type>article</type><title>Photocatalytic Hydrogen Evolution Coupled with Production of Highly Value‐Added Organic Chemicals by a Composite Photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2</title><source>Wiley Online Library Journals Frontfile Complete</source><creator>Zhang, Huan‐Huan ; Zhan, Guo‐Peng ; Liu, Zi‐Kun ; Wu, Chuan‐De</creator><creatorcontrib>Zhang, Huan‐Huan ; Zhan, Guo‐Peng ; Liu, Zi‐Kun ; Wu, Chuan‐De</creatorcontrib><description>Photocatalytic water splitting coupled with the production of highly value‐added organic chemicals is of significant importance, which represents a very promising pathway for transforming green solar energy into chemical energy. Herein, we report a composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, which is highly efficient on prompting water splitting for the production of H2 in the reduction half‐reaction and selective oxidation of organic molecules for the production of highly value‐added organic chemicals in the oxidation half‐reaction under visible light irradiation. The superior photocatalytic properties of the composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2 should be ascribed to coating suspended ion catalyst (SIC), consisting of redox‐active NiII ions in the anionic pores of coordination network MIL‐53‐SO3−, on the surface of photoactive CdIn2S4, which endows photogenerated electron‐hole pairs separate more efficiently for high rate production of H2 and selective production of highly value‐added organic products, demonstrating great potential for practical applications. A composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, consisting of photoactive cadmium indium sulphide core and suspended ion catalyst MIL‐53‐SO3Ni1/2 shell, demonstrates high photocatalytic efficiency and stability in H2 evolution coupled with production of highly value‐added imines under visible light irradiation.</description><identifier>ISSN: 1861-4728</identifier><identifier>EISSN: 1861-471X</identifier><identifier>DOI: 10.1002/asia.202100262</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Chemical energy ; Chemistry ; Clean energy ; Hydrogen evolution ; Light irradiation ; metal-organic frameworks ; Organic chemicals ; Organic chemistry ; Oxidation ; Photocatalysis ; Photocatalysts ; Solar energy ; Sulfur trioxide ; suspended ion catalysts ; Water splitting</subject><ispartof>Chemistry, an Asian journal, 2021-06, Vol.16 (11), p.1499-1506</ispartof><rights>2021 Wiley‐VCH GmbH</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><orcidid>0000-0001-8128-134X</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://onlinelibrary.wiley.com/doi/pdf/10.1002%2Fasia.202100262$$EPDF$$P50$$Gwiley$$H</linktopdf><linktohtml>$$Uhttps://onlinelibrary.wiley.com/doi/full/10.1002%2Fasia.202100262$$EHTML$$P50$$Gwiley$$H</linktohtml><link.rule.ids>314,776,780,1411,27901,27902,45550,45551</link.rule.ids></links><search><creatorcontrib>Zhang, Huan‐Huan</creatorcontrib><creatorcontrib>Zhan, Guo‐Peng</creatorcontrib><creatorcontrib>Liu, Zi‐Kun</creatorcontrib><creatorcontrib>Wu, Chuan‐De</creatorcontrib><title>Photocatalytic Hydrogen Evolution Coupled with Production of Highly Value‐Added Organic Chemicals by a Composite Photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2</title><title>Chemistry, an Asian journal</title><description>Photocatalytic water splitting coupled with the production of highly value‐added organic chemicals is of significant importance, which represents a very promising pathway for transforming green solar energy into chemical energy. Herein, we report a composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, which is highly efficient on prompting water splitting for the production of H2 in the reduction half‐reaction and selective oxidation of organic molecules for the production of highly value‐added organic chemicals in the oxidation half‐reaction under visible light irradiation. The superior photocatalytic properties of the composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2 should be ascribed to coating suspended ion catalyst (SIC), consisting of redox‐active NiII ions in the anionic pores of coordination network MIL‐53‐SO3−, on the surface of photoactive CdIn2S4, which endows photogenerated electron‐hole pairs separate more efficiently for high rate production of H2 and selective production of highly value‐added organic products, demonstrating great potential for practical applications. A composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, consisting of photoactive cadmium indium sulphide core and suspended ion catalyst MIL‐53‐SO3Ni1/2 shell, demonstrates high photocatalytic efficiency and stability in H2 evolution coupled with production of highly value‐added imines under visible light irradiation.</description><subject>Chemical energy</subject><subject>Chemistry</subject><subject>Clean energy</subject><subject>Hydrogen evolution</subject><subject>Light irradiation</subject><subject>metal-organic frameworks</subject><subject>Organic chemicals</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Photocatalysis</subject><subject>Photocatalysts</subject><subject>Solar energy</subject><subject>Sulfur trioxide</subject><subject>suspended ion catalysts</subject><subject>Water splitting</subject><issn>1861-4728</issn><issn>1861-471X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNpNkM9Kw0AQxoMoWKtXzwue0-5ONsnmZgjVFqotVMVb2O5uki1pNuaPJTcfwQfw6XwSUyvFy8x8wze_gc-yrgkeEYxhzGvNR4BhLzw4sQaEecSmPnk9Pc7Azq2Lut5g7AIO2MD6WmamMYI3PO8aLdC0k5VJVYEm7yZvG20KFJm2zJVEO91kaFkZ2YrfvUnQVKdZ3qEXnrfq--MzlLL3LaqUFz0qytRWC57XaN0h3mO2pal1o9C_l3WDIjkrYEVvH2bzHuE6fVktnEdNxnBpnSX9vbr660Pr-W7yFE3t-eJ-FoVzOwUfg514jEnuBolPMEihOKEE-8KXwiOJWlMuAwoKPKaoT0XCmSPWwIGytU8T8BJnaN0cuGVl3lpVN_HGtFXRv4zBdVxMPMLc3hUcXDudqy4uK73lVRcTHO8Tj_fxx8f443A1C4_K-QGMx3-V</recordid><startdate>20210601</startdate><enddate>20210601</enddate><creator>Zhang, Huan‐Huan</creator><creator>Zhan, Guo‐Peng</creator><creator>Liu, Zi‐Kun</creator><creator>Wu, Chuan‐De</creator><general>Wiley Subscription Services, Inc</general><scope>K9.</scope><orcidid>https://orcid.org/0000-0001-8128-134X</orcidid></search><sort><creationdate>20210601</creationdate><title>Photocatalytic Hydrogen Evolution Coupled with Production of Highly Value‐Added Organic Chemicals by a Composite Photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2</title><author>Zhang, Huan‐Huan ; Zhan, Guo‐Peng ; Liu, Zi‐Kun ; Wu, Chuan‐De</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g2702-f688da59f7102dcea14107c7dc61feb4ad942e268e474cfa83cb2a248b74f26f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Chemical energy</topic><topic>Chemistry</topic><topic>Clean energy</topic><topic>Hydrogen evolution</topic><topic>Light irradiation</topic><topic>metal-organic frameworks</topic><topic>Organic chemicals</topic><topic>Organic chemistry</topic><topic>Oxidation</topic><topic>Photocatalysis</topic><topic>Photocatalysts</topic><topic>Solar energy</topic><topic>Sulfur trioxide</topic><topic>suspended ion catalysts</topic><topic>Water splitting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Huan‐Huan</creatorcontrib><creatorcontrib>Zhan, Guo‐Peng</creatorcontrib><creatorcontrib>Liu, Zi‐Kun</creatorcontrib><creatorcontrib>Wu, Chuan‐De</creatorcontrib><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><jtitle>Chemistry, an Asian journal</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Huan‐Huan</au><au>Zhan, Guo‐Peng</au><au>Liu, Zi‐Kun</au><au>Wu, Chuan‐De</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Photocatalytic Hydrogen Evolution Coupled with Production of Highly Value‐Added Organic Chemicals by a Composite Photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2</atitle><jtitle>Chemistry, an Asian journal</jtitle><date>2021-06-01</date><risdate>2021</risdate><volume>16</volume><issue>11</issue><spage>1499</spage><epage>1506</epage><pages>1499-1506</pages><issn>1861-4728</issn><eissn>1861-471X</eissn><abstract>Photocatalytic water splitting coupled with the production of highly value‐added organic chemicals is of significant importance, which represents a very promising pathway for transforming green solar energy into chemical energy. Herein, we report a composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, which is highly efficient on prompting water splitting for the production of H2 in the reduction half‐reaction and selective oxidation of organic molecules for the production of highly value‐added organic chemicals in the oxidation half‐reaction under visible light irradiation. The superior photocatalytic properties of the composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2 should be ascribed to coating suspended ion catalyst (SIC), consisting of redox‐active NiII ions in the anionic pores of coordination network MIL‐53‐SO3−, on the surface of photoactive CdIn2S4, which endows photogenerated electron‐hole pairs separate more efficiently for high rate production of H2 and selective production of highly value‐added organic products, demonstrating great potential for practical applications. A composite photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2, consisting of photoactive cadmium indium sulphide core and suspended ion catalyst MIL‐53‐SO3Ni1/2 shell, demonstrates high photocatalytic efficiency and stability in H2 evolution coupled with production of highly value‐added imines under visible light irradiation.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/asia.202100262</doi><tpages>8</tpages><orcidid>https://orcid.org/0000-0001-8128-134X</orcidid></addata></record>
fulltext fulltext
identifier ISSN: 1861-4728
ispartof Chemistry, an Asian journal, 2021-06, Vol.16 (11), p.1499-1506
issn 1861-4728
1861-471X
language eng
recordid cdi_proquest_journals_2535016185
source Wiley Online Library Journals Frontfile Complete
subjects Chemical energy
Chemistry
Clean energy
Hydrogen evolution
Light irradiation
metal-organic frameworks
Organic chemicals
Organic chemistry
Oxidation
Photocatalysis
Photocatalysts
Solar energy
Sulfur trioxide
suspended ion catalysts
Water splitting
title Photocatalytic Hydrogen Evolution Coupled with Production of Highly Value‐Added Organic Chemicals by a Composite Photocatalyst CdIn2S4@MIL‐53‐SO3Ni1/2
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-31T23%3A59%3A57IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_wiley&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Photocatalytic%20Hydrogen%20Evolution%20Coupled%20with%20Production%20of%20Highly%20Value%E2%80%90Added%20Organic%20Chemicals%20by%20a%20Composite%20Photocatalyst%20CdIn2S4@MIL%E2%80%9053%E2%80%90SO3Ni1/2&rft.jtitle=Chemistry,%20an%20Asian%20journal&rft.au=Zhang,%20Huan%E2%80%90Huan&rft.date=2021-06-01&rft.volume=16&rft.issue=11&rft.spage=1499&rft.epage=1506&rft.pages=1499-1506&rft.issn=1861-4728&rft.eissn=1861-471X&rft_id=info:doi/10.1002/asia.202100262&rft_dat=%3Cproquest_wiley%3E2535016185%3C/proquest_wiley%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2535016185&rft_id=info:pmid/&rfr_iscdi=true