Light-induced borylation: developments and mechanistic insights

Organoboron compounds are very important derivatives because of their profound impacts on medicinal, biological as well as industrial applications. The development of several novel borylation methodologies has achieved momentous interest among synthetic chemists. In this scenario, eco-friendly light...

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Veröffentlicht in:Organic & biomolecular chemistry 2021-05, Vol.19 (2), p.4397-4428
Hauptverfasser: Lai, Dipti, Ghosh, Sumit, Hajra, Alakananda
Format: Artikel
Sprache:eng
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Zusammenfassung:Organoboron compounds are very important derivatives because of their profound impacts on medicinal, biological as well as industrial applications. The development of several novel borylation methodologies has achieved momentous interest among synthetic chemists. In this scenario, eco-friendly light-induced borylation is progressively becoming one of the best synthetic tools in recent days to prepare organoboronic ester and acid derivatives based on green chemistry rules. In this article, we have discussed all the UV- and visible-light-induced borylation strategies developed in the last decade. Furthermore, special attention is given to the mechanisms of these borylation methodologies for better understanding of reaction insights. This perspective delineates light-induced borylation methodologies, which have been developed in the last 10 years. Mechanistic insights have been explored throughout the article for these UV- and visible-light-induced borylation reactions.
ISSN:1477-0520
1477-0539
DOI:10.1039/d1ob00323b