Brønsted acid catalyzed radical addition to quinone methides

A fundamental quest for alkyl radical generation under mild conditions through photoinduced Brønsted acid catalysis is addressed. The optimized protocol does not require any organic dyes or transition metal photocatalyst. Under blue light irradiation with diphenyl phosphate as a catalyst and dihydropyridine derivatives as a radical source, functionalized arylmethane derivatives are obtained in high yield. A fundamental quest for alkyl radical generation under mild conditions through photoinduced Brønsted acid catalysis is addressed.