Visible Light Enabled Formal Cross Silyl Benzoin Reaction as an Access to α‐Hydroxyketones

Visible Light Enabled Formal Cross Silyl Benzoin Reaction as an Access to α‐Hydroxyketones

In this work, a visible‐light enabled coupling of acylsilanes with aldehydes to give a range of cross‐benzoin type products α‐hydroxyketones is described. The reaction could proceed at ambient temperature, with the irradiation of low energy visible light, and without addition of photosensitizer or a...

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Veröffentlicht in:Advanced synthesis & catalysis 2021-05, Vol.363 (10), p.2573-2577
Hauptverfasser: Ma, Liyao, Yu, Yinghua, Xin, Luoting, Zhu, Lei, Xia, Jiajin, Ou, Pengcheng, Huang, Xueliang
Format: Artikel
Sprache:eng
Schlagworte:
acylsilanes
additive-free
Additives
Aldehydes
Ambient temperature
Benzoin
cross-benzoin reaction
visible-light
α-hydroxyketones
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Zusammenfassung:In this work, a visible‐light enabled coupling of acylsilanes with aldehydes to give a range of cross‐benzoin type products α‐hydroxyketones is described. The reaction could proceed at ambient temperature, with the irradiation of low energy visible light, and without addition of photosensitizer or any other additives.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202100186