Muscle Fibers Inspired High‐Performance Piezoelectric Textiles for Wearable Physiological Monitoring

The next‐generation wearable biosensors with highly biocompatible, stretchable, and robust features are expected to enable the change of the current reactive and disease‐centric healthcare system to a personalized model with a focus on disease prevention and health promotion. Herein, a muscle‐fiber‐inspired nonwoven piezoelectric textile with tunable mechanical properties for wearable physiological monitoring is developed. To mimic the muscle fibers, polydopamine (PDA) is dispersed into the electrospun barium titanate/polyvinylidene fluoride (BTO/PVDF) nanofibers to enhance the interfacial‐adhesion, mechanical strength, and piezoelectric properties. Such improvements are both experimentally observed via mechanical characterization and theoretically verified by the phase‐field simulation. Taking the PDA@BTO/PVDF nanofibers as the building blocks, a nonwoven light‐weight piezoelectric textile is fabricated, which hold an outstanding sensitivity (3.95 V N−1) and long‐term stability (