Allowing for Local Thermodynamic Non-Equilibrium in the Vibrational Bands of Carbon Dioxide Molecules in the Radiation Block of the Model of the General Circulation of Earth’s Atmosphere

A way of calculating the field of solar radiation in Earth’s atmosphere is described that considers the thermodynamic non-equilibrium in the vibrational bands of CO 2 and O 3 . The proposed technique allows calculations with high spectral resolution (line by line), along with parameterizations of the optical parameters of the Earth’s upper atmosphere that can be used in calculating the field of solar radiation.