Brewer’s grains with different pretreatments used as bio-adsorbents for the removal of Congo red dye from aqueous solution

Brewer’s grains (BG), a by-product of the beer industry, were first pretreated by sulfuric acid, sodium hydroxide, and white-rot fungus Coriolus versicolor for the preparation of bio-adsorbents BGPH, BGPOH, and BGPB, respectively. All bio-adsorbents were rich in hydroxyl groups and could adsorb Cong...

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Veröffentlicht in:Bioresources 2020-08, Vol.15 (3), p.6928-6940
Hauptverfasser: Wu, Jianguo, Zhang, Zhao, Xu, Jintao, Lu, Xuanxian, Wang, Chi, Xu, Hui, Yuan, Haihang, Zhang, Ji
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container_end_page 6940
container_issue 3
container_start_page 6928
container_title Bioresources
container_volume 15
creator Wu, Jianguo
Zhang, Zhao
Xu, Jintao
Lu, Xuanxian
Wang, Chi
Xu, Hui
Yuan, Haihang
Zhang, Ji
description Brewer’s grains (BG), a by-product of the beer industry, were first pretreated by sulfuric acid, sodium hydroxide, and white-rot fungus Coriolus versicolor for the preparation of bio-adsorbents BGPH, BGPOH, and BGPB, respectively. All bio-adsorbents were rich in hydroxyl groups and could adsorb Congo red dye from aqueous solution, and BGPOH worked better than the others. The order of maximum equilibrium adsorption capacity of bio-adsorbents for Congo red was BGPOH > BGPH > BGPB. The Langmuir, Freundlich, and Temkin adsorption isotherm models all fit well with the experimental data. The negative Gibbs free energy change meant that the adsorption was spontaneous, and lower temperature was useful for the adsorption of Congo red onto the bio-adsorbents. The pseudo first-order and second-order kinetics models fit well with the experimental data, and the second-order kinetics model fit better, which indicated the adsorption was controlled by diffusion phenomena. Brewer’s grains with the three pretreatments could be used as efficient adsorbents for the treatment of dye wastewater.
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All bio-adsorbents were rich in hydroxyl groups and could adsorb Congo red dye from aqueous solution, and BGPOH worked better than the others. The order of maximum equilibrium adsorption capacity of bio-adsorbents for Congo red was BGPOH &gt; BGPH &gt; BGPB. The Langmuir, Freundlich, and Temkin adsorption isotherm models all fit well with the experimental data. The negative Gibbs free energy change meant that the adsorption was spontaneous, and lower temperature was useful for the adsorption of Congo red onto the bio-adsorbents. The pseudo first-order and second-order kinetics models fit well with the experimental data, and the second-order kinetics model fit better, which indicated the adsorption was controlled by diffusion phenomena. Brewer’s grains with the three pretreatments could be used as efficient adsorbents for the treatment of dye wastewater.</description><identifier>ISSN: 1930-2126</identifier><identifier>EISSN: 1930-2126</identifier><identifier>DOI: 10.15376/biores.15.3.6928-6940</identifier><language>eng</language><publisher>Raleigh: North Carolina State University</publisher><subject>Activated carbon ; Adsorbents ; Adsorption ; Agricultural biotechnology ; Aqueous solutions ; Beer ; Breweries ; Caustic soda ; Cellulose ; Dyes ; Equilibrium ; Experimental data ; Free energy ; Fungi ; Gibbs free energy ; Hydrocarbons ; Hydroxyl groups ; Industrial wastewater ; Kinetics ; Lignin ; Sodium ; Sodium hydroxide ; Spectrum analysis ; Sulfuric acid ; Vibration ; Wastewater treatment ; White rot fungi</subject><ispartof>Bioresources, 2020-08, Vol.15 (3), p.6928-6940</ispartof><rights>2020. 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Brewer’s grains with the three pretreatments could be used as efficient adsorbents for the treatment of dye wastewater.</abstract><cop>Raleigh</cop><pub>North Carolina State University</pub><doi>10.15376/biores.15.3.6928-6940</doi><tpages>13</tpages><oa>free_for_read</oa></addata></record>
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subjects Activated carbon
Adsorbents
Adsorption
Agricultural biotechnology
Aqueous solutions
Beer
Breweries
Caustic soda
Cellulose
Dyes
Equilibrium
Experimental data
Free energy
Fungi
Gibbs free energy
Hydrocarbons
Hydroxyl groups
Industrial wastewater
Kinetics
Lignin
Sodium
Sodium hydroxide
Spectrum analysis
Sulfuric acid
Vibration
Wastewater treatment
White rot fungi
title Brewer’s grains with different pretreatments used as bio-adsorbents for the removal of Congo red dye from aqueous solution
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