STRUCTURE OF DIETHYLENETRIAMMONIUM HEXACHLOROIRIDATE(IV) COMPLEXES
The crystal structures of salts (DienH 3 ) 4 [IrCl 6 ] 5 Cl 2 ( I ), (DienH 3 )[IrCl 6 ]Cl ( II ), and (DienH 3 ) 2 [IrCl 6 ] 3 ( III ) is triple protonated diethylenetriamine). Crystal data for I : a = 26.891(2) Å, b = 6.9379(3) Å, c = 35.031(3) Å, β = 100.758(2)°, space group C 2/ c , Z = 8, V...
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| Veröffentlicht in: | Journal of structural chemistry 2021-03, Vol.62 (3), p.422-430 |
|---|---|
| Hauptverfasser: | , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
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| Zusammenfassung: | The crystal structures of salts (DienH
3
)
4
[IrCl
6
]
5
Cl
2
(
I
), (DienH
3
)[IrCl
6
]Cl (
II
), and (DienH
3
)
2
[IrCl
6
]
3
(
III
)
is triple protonated diethylenetriamine). Crystal data for
I
:
a
= 26.891(2) Å,
b
= 6.9379(3) Å,
c
= 35.031(3) Å, β = 100.758(2)°, space group
C
2/
c
,
Z
= 8,
V
= 6420.8(8) Å
3
, ρ
calc
= 2.607 g/cm
3
;
II:
a
= 6.8598(3) Å,
b
= 23.2075(11) Å,
c
= 9.5730(4) Å, β = 90.240(2)°, space group
P
2
1
/
n
,
Z
= 4,
V
= 1524.00(12) Å
3
, ρ
calc
= 2.382 g/cm
3
;
III:
a
= 12.4277(3) Å,
b
= 19.6134(5) Å,
c
= 14.3613(3) Å, β = 98.260(1)°, space group
P
2
1
/
n
,
Z
= 4,
V
= 3464.25(14) Å
3
, ρ
calc
= 2.736 g/cm
3
. |
|---|---|
| ISSN: | 0022-4766 1573-8779 |
| DOI: | 10.1134/S0022476621030082 |