Reactions of Cage Substrates with Sulfur Nucleophiles

Reactions of Cage Substrates with Sulfur Nucleophiles

Reactions of alcohols of the adamantane series and adamantan-1-yl nitrates with sulfur nucleophiles in 94% sulfuric acid afforded a number of new sulfur-containing adamantane derivatives such as carbamo­thioates, isothiocyanates, and carbamodithioates. Di(adamantan-1-yl) disulfide was synthesized by...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Russian journal of organic chemistry 2021-03, Vol.57 (3), p.355-363
Hauptverfasser: Klimochkin, Yu. N., Ivleva, E. A., Shiryaev, V. A.
Format: Artikel
Sprache:eng
Schlagworte:
Alcohols
Chemical synthesis
Chemistry
Chemistry and Materials Science
Nitrates
Nucleophiles
Organic Chemistry
Sodium sulfide
Substrates
Sulfur
Sulfuric acid
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Reactions of alcohols of the adamantane series and adamantan-1-yl nitrates with sulfur nucleophiles in 94% sulfuric acid afforded a number of new sulfur-containing adamantane derivatives such as carbamo­thioates, isothiocyanates, and carbamodithioates. Di(adamantan-1-yl) disulfide was synthesized by reaction of admantan-1-yl nitrate with sodium sulfide nonahydrate in 94% sulfuric acid.
ISSN:1070-4280
1608-3393
DOI:10.1134/S1070428021030052