Determination of the Impurity Level of High-Purity Arsine by Chromatography–Mass-Spectrometry
The impurity composition of arsine is studied by gas chromatography – mass-spectrometry. Impu-rities of permanent gases; carbon dioxide; hydrides; saturated, unsaturated, and aromatic hydrocarbons C 1 –C 6 ; halogenated hydrocarbons; sulfur compounds; and arsine and diarsine alkyl derivatives are de...
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| Veröffentlicht in: | Journal of analytical chemistry (New York, N.Y.) N.Y.), 2021-03, Vol.76 (3), p.347-354 |
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| container_title | Journal of analytical chemistry (New York, N.Y.) |
| container_volume | 76 |
| creator | Sozin, A. Yu Sorochkina, T. G. Chernova, O. Yu Kotkov, A. P. Grishnova, N. D. Polezhaev, D. M. Pushkarev, G. V. Ermolaev, S. V. |
| description | The impurity composition of arsine is studied by gas chromatography
–
mass-spectrometry. Impu-rities of permanent gases; carbon dioxide; hydrides; saturated, unsaturated, and aromatic hydrocarbons C
1
–C
6
; halogenated hydrocarbons; sulfur compounds; and arsine and diarsine alkyl derivatives are determined. The impurity level of high-purity arsine is 10
–6
–10
–5
vol %. Impurity concentrations in arsine after synthesis and in the fractions extracted in the course of its rectification are rather high and lie in the range 10
–6
–0.1 vol %. The limits of detection for impurities are 2 × 10
–7
–2 × 10
–4
vol %. |
| doi_str_mv | 10.1134/S1061934821030138 |
| format | Article |
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–
mass-spectrometry. Impu-rities of permanent gases; carbon dioxide; hydrides; saturated, unsaturated, and aromatic hydrocarbons C
1
–C
6
; halogenated hydrocarbons; sulfur compounds; and arsine and diarsine alkyl derivatives are determined. The impurity level of high-purity arsine is 10
–6
–10
–5
vol %. Impurity concentrations in arsine after synthesis and in the fractions extracted in the course of its rectification are rather high and lie in the range 10
–6
–0.1 vol %. The limits of detection for impurities are 2 × 10
–7
–2 × 10
–4
vol %.</description><identifier>ISSN: 1061-9348</identifier><identifier>EISSN: 1608-3199</identifier><identifier>DOI: 10.1134/S1061934821030138</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Analytical Chemistry ; Aromatic hydrocarbons ; Arsenic compounds ; Carbon dioxide ; Chemistry ; Chemistry and Materials Science ; Chromatography ; Gas chromatography ; Hydrocarbons ; Impurities ; Purity ; Scientific imaging ; Solar energy ; Spectrometry ; Spectroscopy ; Spectrum analysis ; Sulfur compounds</subject><ispartof>Journal of analytical chemistry (New York, N.Y.), 2021-03, Vol.76 (3), p.347-354</ispartof><rights>Pleiades Publishing, Ltd. 2021. ISSN 1061-9348, Journal of Analytical Chemistry, 2021, Vol. 76, No. 3, pp. 347–354. © Pleiades Publishing, Ltd., 2021. Russian Text © The Author(s), 2021, published in Zhurnal Analiticheskoi Khimii, 2021, Vol. 76, No. 3, pp. 253–260.</rights><rights>COPYRIGHT 2021 Springer</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><cites>FETCH-LOGICAL-c407t-6eeabe38d9f29dafda28dbcb218382b2fc94a3f52b4e0ba3231bc79c7b21c34f3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1061934821030138$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1061934821030138$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Sozin, A. Yu</creatorcontrib><creatorcontrib>Sorochkina, T. G.</creatorcontrib><creatorcontrib>Chernova, O. Yu</creatorcontrib><creatorcontrib>Kotkov, A. P.</creatorcontrib><creatorcontrib>Grishnova, N. D.</creatorcontrib><creatorcontrib>Polezhaev, D. M.</creatorcontrib><creatorcontrib>Pushkarev, G. V.</creatorcontrib><creatorcontrib>Ermolaev, S. V.</creatorcontrib><title>Determination of the Impurity Level of High-Purity Arsine by Chromatography–Mass-Spectrometry</title><title>Journal of analytical chemistry (New York, N.Y.)</title><addtitle>J Anal Chem</addtitle><description>The impurity composition of arsine is studied by gas chromatography
–
mass-spectrometry. Impu-rities of permanent gases; carbon dioxide; hydrides; saturated, unsaturated, and aromatic hydrocarbons C
1
–C
6
; halogenated hydrocarbons; sulfur compounds; and arsine and diarsine alkyl derivatives are determined. The impurity level of high-purity arsine is 10
–6
–10
–5
vol %. Impurity concentrations in arsine after synthesis and in the fractions extracted in the course of its rectification are rather high and lie in the range 10
–6
–0.1 vol %. The limits of detection for impurities are 2 × 10
–7
–2 × 10
–4
vol %.</description><subject>Analytical Chemistry</subject><subject>Aromatic hydrocarbons</subject><subject>Arsenic compounds</subject><subject>Carbon dioxide</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chromatography</subject><subject>Gas chromatography</subject><subject>Hydrocarbons</subject><subject>Impurities</subject><subject>Purity</subject><subject>Scientific imaging</subject><subject>Solar energy</subject><subject>Spectrometry</subject><subject>Spectroscopy</subject><subject>Spectrum analysis</subject><subject>Sulfur compounds</subject><issn>1061-9348</issn><issn>1608-3199</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kcFqGzEQhpfSQtOkD9DbQk85bKqR1mvpaNwmMTg0xOlZaLWjtYJ3tZHkkL3lHfqGfZLKOBBMXeag4f-_fwQzWfYFyAUAK7-tgFQgWMkpEEaA8XfZCVSEFwyEeJ_6ZBc7_2P2KYQHQojgUJ1k8jtG9J3tVbSuz53J4xrzRTdsvY1jvsQn3OzUa9uui9u9OPPB9pjXYz5fe9ep6FqvhvX45-X3jQqhWA2oYzIw-vEs-2DUJuDn1_c0-3X5435-XSx_Xi3ms2WhSzKNRYWoamS8EYaKRplGUd7UuqbAGac1NVqUipkJrUsktWKUQa2nQk8ToVlp2Gn2dT938O5xiyHKB7f1ffpS0glJOykJhzeqVRuUtjcueqU7G7ScVZMKoJpMRaKKI1SLPXq1cT0am-QD_uIIn6rBzuqjgfODQGIiPsdWbUOQi9XdIQt7VnsXgkcjB2875UcJRO5OL_85fcrQfSYktm_Rvy3j_6G_Xyyvlw</recordid><startdate>20210301</startdate><enddate>20210301</enddate><creator>Sozin, A. Yu</creator><creator>Sorochkina, T. G.</creator><creator>Chernova, O. Yu</creator><creator>Kotkov, A. P.</creator><creator>Grishnova, N. D.</creator><creator>Polezhaev, D. M.</creator><creator>Pushkarev, G. V.</creator><creator>Ermolaev, S. V.</creator><general>Pleiades Publishing</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope></search><sort><creationdate>20210301</creationdate><title>Determination of the Impurity Level of High-Purity Arsine by Chromatography–Mass-Spectrometry</title><author>Sozin, A. Yu ; Sorochkina, T. G. ; Chernova, O. Yu ; Kotkov, A. P. ; Grishnova, N. D. ; Polezhaev, D. M. ; Pushkarev, G. V. ; Ermolaev, S. V.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c407t-6eeabe38d9f29dafda28dbcb218382b2fc94a3f52b4e0ba3231bc79c7b21c34f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Analytical Chemistry</topic><topic>Aromatic hydrocarbons</topic><topic>Arsenic compounds</topic><topic>Carbon dioxide</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chromatography</topic><topic>Gas chromatography</topic><topic>Hydrocarbons</topic><topic>Impurities</topic><topic>Purity</topic><topic>Scientific imaging</topic><topic>Solar energy</topic><topic>Spectrometry</topic><topic>Spectroscopy</topic><topic>Spectrum analysis</topic><topic>Sulfur compounds</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sozin, A. Yu</creatorcontrib><creatorcontrib>Sorochkina, T. G.</creatorcontrib><creatorcontrib>Chernova, O. Yu</creatorcontrib><creatorcontrib>Kotkov, A. P.</creatorcontrib><creatorcontrib>Grishnova, N. D.</creatorcontrib><creatorcontrib>Polezhaev, D. M.</creatorcontrib><creatorcontrib>Pushkarev, G. V.</creatorcontrib><creatorcontrib>Ermolaev, S. V.</creatorcontrib><collection>CrossRef</collection><collection>Gale In Context: Science</collection><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sozin, A. Yu</au><au>Sorochkina, T. G.</au><au>Chernova, O. Yu</au><au>Kotkov, A. P.</au><au>Grishnova, N. D.</au><au>Polezhaev, D. M.</au><au>Pushkarev, G. V.</au><au>Ermolaev, S. V.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Determination of the Impurity Level of High-Purity Arsine by Chromatography–Mass-Spectrometry</atitle><jtitle>Journal of analytical chemistry (New York, N.Y.)</jtitle><stitle>J Anal Chem</stitle><date>2021-03-01</date><risdate>2021</risdate><volume>76</volume><issue>3</issue><spage>347</spage><epage>354</epage><pages>347-354</pages><issn>1061-9348</issn><eissn>1608-3199</eissn><abstract>The impurity composition of arsine is studied by gas chromatography
–
mass-spectrometry. Impu-rities of permanent gases; carbon dioxide; hydrides; saturated, unsaturated, and aromatic hydrocarbons C
1
–C
6
; halogenated hydrocarbons; sulfur compounds; and arsine and diarsine alkyl derivatives are determined. The impurity level of high-purity arsine is 10
–6
–10
–5
vol %. Impurity concentrations in arsine after synthesis and in the fractions extracted in the course of its rectification are rather high and lie in the range 10
–6
–0.1 vol %. The limits of detection for impurities are 2 × 10
–7
–2 × 10
–4
vol %.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1061934821030138</doi><tpages>8</tpages></addata></record> |
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| subjects | Analytical Chemistry Aromatic hydrocarbons Arsenic compounds Carbon dioxide Chemistry Chemistry and Materials Science Chromatography Gas chromatography Hydrocarbons Impurities Purity Scientific imaging Solar energy Spectrometry Spectroscopy Spectrum analysis Sulfur compounds |
| title | Determination of the Impurity Level of High-Purity Arsine by Chromatography–Mass-Spectrometry |
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