Overcharge protection of lithium-ion batteries with phenothiazine redox shuttles
Overcharge in lithium-ion batteries (LIBs) can be mitigated using electron-donating small molecules with oxidation potentials just above the end-of-charge potential of the electrochemical cell. These additives function by oxidizing at the cathode/electrolyte interface, forming radical cations, and a...
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| Veröffentlicht in: | New journal of chemistry 2021-03, Vol.45 (8), p.375-3755 |
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| container_title | New journal of chemistry |
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| creator | Odom, Susan A |
| description | Overcharge in lithium-ion batteries (LIBs) can be mitigated using electron-donating small molecules with oxidation potentials just above the end-of-charge potential of the electrochemical cell. These additives function by oxidizing at the cathode/electrolyte interface, forming radical cations, and are then reduced at the anode/electrolyte interface, becoming neutral again. A variety of redox shuttles have been reported since 2005 including derivatives of TEMPO, alkoxybenzene, and phenothiazine. This perspective focuses on phenothiazines redox shuttles and their performance in LIBs.
Overcharge protection of Li-ion batteries with a variety of phenothiazine derivatives. |
| doi_str_mv | 10.1039/d0nj05935h |
| format | Article |
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| ispartof | New journal of chemistry, 2021-03, Vol.45 (8), p.375-3755 |
| issn | 1144-0546 1369-9261 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| subjects | Additives Electrochemical cells Electrolytes Lithium Lithium-ion batteries Oxidation Phenothiazines Rechargeable batteries |
| title | Overcharge protection of lithium-ion batteries with phenothiazine redox shuttles |
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