Spray Synthesis of Photonic Crystal Based Automotive Coatings with Bright and Angular‐Dependent Structural Colors

It is a challenge to prepare photonic crystal (PC) automotive coatings via spraying colloidal solutions because the fast fabrication tends to produce amorphous photonic crystals with faint colors. Here, a two‐step spraying process followed by thermal curing is developed to prepare waterproof PC coatings with bright, uniform, and angular‐dependent structural colors. The solvents in PC paint are studied to achieve a quick formation of liquid PC intermediate, which transformed into a highly crystalline PC coating. Thanks to the narrow and intense reflections, the as‐made coatings present colors with high saturation, including the red/yellow/green/blue colors achieved by tuning the particle size, and many spectral/non‐spectral colors via the mixing of base colors. Meanwhile, patterned or fully covered PC coatings with good chemical and mechanical stability can be prepared on different substrates, where the shiny colors changing with the viewing angles or the surface curvatures offer a new choice for personalized automotive coatings. Photonic crystal (PC) automotive coatings with bright, durable, and angular‐dependent structural colors are prepared via a two‐step spraying process followed by thermal curing. The solvents in the PC paint are studied to achieve a quick formation of the liquid PC intermediate, which transforms into a highly crystalline PC structure.