Continuous-flow step-economical synthesis of thiuram disulfides via visible-light photocatalytic aerobic oxidation

Continuous-flow step-economical synthesis of thiuram disulfides via visible-light photocatalytic aerobic oxidation

A continuous-flow photocatalytic synthesis of the industrially important thiuram disulfides has been developed, utilizing O 2 as the oxidant and Eosin Y as the photoredox catalyst. This highly atom- and step-economical method features much reduced reaction time as well as excellent product yield and...

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Veröffentlicht in:Green chemistry : an international journal and green chemistry resource : GC 2021-01, Vol.23 (3), p.1280-1285
Hauptverfasser: Xu, Hao-Xing, Zhao, Ze-Run, Patehebieke, Yeersen, Chen, Qian-Qian, Fu, Shun-Guo, Chang, Shuai-Jun, Zhang, Xu-Xu, Zhang, Zhi-Liang, Wang, Xiao
Format: Artikel
Sprache:eng
Schlagworte:
Catalysts
Continuous flow
Disulfides
Green chemistry
Industrial production
Oxidants
Oxidation
Oxidizing agents
Photocatalysis
Photoredox catalysis
Reaction time
Synthesis
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Beschreibung
Zusammenfassung:A continuous-flow photocatalytic synthesis of the industrially important thiuram disulfides has been developed, utilizing O 2 as the oxidant and Eosin Y as the photoredox catalyst. This highly atom- and step-economical method features much reduced reaction time as well as excellent product yield and purity, making it a sustainable and potentially scalable process for industrial production.
ISSN:1463-9262
1463-9270
DOI:10.1039/D0GC04270F