Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide
Сopper(II) nitrate reacts in ethanol with 2-(2-hydroxybenzylidene)- N -(prop-2-en-1-yl)hydrazinecarbothioamide H 2 L in an 1 : 1 molar ratio to form the coordination compound Cu(HL)NO 3 ·H 2 O. The introduction of amines [imidazole (Im), 3,5-dibromopyridine (3,5-Br 2 Py), and 4-methylpyridine (4-Pic...
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| Veröffentlicht in: | Russian journal of general chemistry 2021, Vol.91 (1), p.98-107 |
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| container_title | Russian journal of general chemistry |
| container_volume | 91 |
| creator | Gulea, А. P. Graur, V. О. Ulchina, Ia. I. Bourosh, P. N. Smaglii, V. A. Garbuz, O. S. Tsapkov, V. I. |
| description | Сopper(II) nitrate reacts in ethanol with 2-(2-hydroxybenzylidene)-
N
-(prop-2-en-1-yl)hydrazinecarbothioamide H
2
L in an 1 : 1 molar ratio to form the coordination compound Cu(HL)NO
3
·H
2
O. The introduction of amines [imidazole (Im), 3,5-dibromopyridine (3,5-Br
2
Py), and 4-methylpyridine (4-Pic)] into the reaction mixture in a molar ratio 1 : 1 : 2 leads to the formation of CuA(HL)NO
3
·
n
H
2
O [A = Im, 3,5-Br
2
Py, 4-Pic;
n
= 0, 3] complexes. The structure of the obtained compounds was determined by X-ray structural analysis. The synthesized complexes exhibit antimicrobial, antifungal, antioxidant, and anticancer activities. |
| doi_str_mv | 10.1134/S1070363221010114 |
| format | Article |
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N
-(prop-2-en-1-yl)hydrazinecarbothioamide H
2
L in an 1 : 1 molar ratio to form the coordination compound Cu(HL)NO
3
·H
2
O. The introduction of amines [imidazole (Im), 3,5-dibromopyridine (3,5-Br
2
Py), and 4-methylpyridine (4-Pic)] into the reaction mixture in a molar ratio 1 : 1 : 2 leads to the formation of CuA(HL)NO
3
·
n
H
2
O [A = Im, 3,5-Br
2
Py, 4-Pic;
n
= 0, 3] complexes. The structure of the obtained compounds was determined by X-ray structural analysis. The synthesized complexes exhibit antimicrobial, antifungal, antioxidant, and anticancer activities.</description><identifier>ISSN: 1070-3632</identifier><identifier>EISSN: 1608-3350</identifier><identifier>DOI: 10.1134/S1070363221010114</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Amines ; Anticancer properties ; Antiinfectives and antibacterials ; Antioxidants ; Biological activity ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Coordination compounds ; Copper ; Copper compounds ; Ethanol ; Fungicides ; Imidazole ; Structural analysis</subject><ispartof>Russian journal of general chemistry, 2021, Vol.91 (1), p.98-107</ispartof><rights>Pleiades Publishing, Ltd. 2021</rights><rights>Pleiades Publishing, Ltd. 2021.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c316t-74484af6eade6e3251f104de029c3f114878c233d6a20b55bbd656ea772d77073</citedby><cites>FETCH-LOGICAL-c316t-74484af6eade6e3251f104de029c3f114878c233d6a20b55bbd656ea772d77073</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1070363221010114$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1070363221010114$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Gulea, А. P.</creatorcontrib><creatorcontrib>Graur, V. О.</creatorcontrib><creatorcontrib>Ulchina, Ia. I.</creatorcontrib><creatorcontrib>Bourosh, P. N.</creatorcontrib><creatorcontrib>Smaglii, V. A.</creatorcontrib><creatorcontrib>Garbuz, O. S.</creatorcontrib><creatorcontrib>Tsapkov, V. I.</creatorcontrib><title>Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide</title><title>Russian journal of general chemistry</title><addtitle>Russ J Gen Chem</addtitle><description>Сopper(II) nitrate reacts in ethanol with 2-(2-hydroxybenzylidene)-
N
-(prop-2-en-1-yl)hydrazinecarbothioamide H
2
L in an 1 : 1 molar ratio to form the coordination compound Cu(HL)NO
3
·H
2
O. The introduction of amines [imidazole (Im), 3,5-dibromopyridine (3,5-Br
2
Py), and 4-methylpyridine (4-Pic)] into the reaction mixture in a molar ratio 1 : 1 : 2 leads to the formation of CuA(HL)NO
3
·
n
H
2
O [A = Im, 3,5-Br
2
Py, 4-Pic;
n
= 0, 3] complexes. The structure of the obtained compounds was determined by X-ray structural analysis. The synthesized complexes exhibit antimicrobial, antifungal, antioxidant, and anticancer activities.</description><subject>Amines</subject><subject>Anticancer properties</subject><subject>Antiinfectives and antibacterials</subject><subject>Antioxidants</subject><subject>Biological activity</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Coordination compounds</subject><subject>Copper</subject><subject>Copper compounds</subject><subject>Ethanol</subject><subject>Fungicides</subject><subject>Imidazole</subject><subject>Structural analysis</subject><issn>1070-3632</issn><issn>1608-3350</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><recordid>eNp1kUtPwzAMxysEEs8PwC0Sl00ikEdfO44J2KQBh8G5Sht3y9QlJUmB8sn4eGQaEgeEfLAt__62ZUfROSVXlPL4ekFJRnjKGaMkGI33oiOakhxznpD9EIcy3tYPo2Pn1iRAJGVH0dei134FTrlLtPC2q3xn4RIJLdGNMo1Zqko0aFx59aZ8j0yNHtQHSDxXyy0z3igNeGK0F0orvUQT07ZgB7PZMITGSqWFV0aHZNOaTkuH3pVfIYYHDE97ac1HX4L-7BslQcMQP-JBa02LGQaNKe6b4SpQ4jOMqYQtjV8pIzYBPo0OatE4OPvxJ9HL3e3zZIrnT_ezyXiOK05Tj7M4zmNRpyAkpMBZQmtKYgmEjSpehzvlWV4xzmUqGCmTpCxlmgQ6y5jMMpLxk-hi1zes9dqB88XadFaHkQWL8xElCeGjQNEdVVnjnIW6aK3aCNsXlBTbBxV_HhQ0bKdxgdVLsL-d_xd9A1PUk1k</recordid><startdate>2021</startdate><enddate>2021</enddate><creator>Gulea, А. P.</creator><creator>Graur, V. О.</creator><creator>Ulchina, Ia. I.</creator><creator>Bourosh, P. N.</creator><creator>Smaglii, V. A.</creator><creator>Garbuz, O. S.</creator><creator>Tsapkov, V. I.</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>2021</creationdate><title>Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide</title><author>Gulea, А. P. ; Graur, V. О. ; Ulchina, Ia. I. ; Bourosh, P. N. ; Smaglii, V. A. ; Garbuz, O. S. ; Tsapkov, V. I.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c316t-74484af6eade6e3251f104de029c3f114878c233d6a20b55bbd656ea772d77073</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2021</creationdate><topic>Amines</topic><topic>Anticancer properties</topic><topic>Antiinfectives and antibacterials</topic><topic>Antioxidants</topic><topic>Biological activity</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Coordination compounds</topic><topic>Copper</topic><topic>Copper compounds</topic><topic>Ethanol</topic><topic>Fungicides</topic><topic>Imidazole</topic><topic>Structural analysis</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gulea, А. P.</creatorcontrib><creatorcontrib>Graur, V. О.</creatorcontrib><creatorcontrib>Ulchina, Ia. I.</creatorcontrib><creatorcontrib>Bourosh, P. N.</creatorcontrib><creatorcontrib>Smaglii, V. A.</creatorcontrib><creatorcontrib>Garbuz, O. S.</creatorcontrib><creatorcontrib>Tsapkov, V. I.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian journal of general chemistry</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gulea, А. P.</au><au>Graur, V. О.</au><au>Ulchina, Ia. I.</au><au>Bourosh, P. N.</au><au>Smaglii, V. A.</au><au>Garbuz, O. S.</au><au>Tsapkov, V. I.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide</atitle><jtitle>Russian journal of general chemistry</jtitle><stitle>Russ J Gen Chem</stitle><date>2021</date><risdate>2021</risdate><volume>91</volume><issue>1</issue><spage>98</spage><epage>107</epage><pages>98-107</pages><issn>1070-3632</issn><eissn>1608-3350</eissn><abstract>Сopper(II) nitrate reacts in ethanol with 2-(2-hydroxybenzylidene)-
N
-(prop-2-en-1-yl)hydrazinecarbothioamide H
2
L in an 1 : 1 molar ratio to form the coordination compound Cu(HL)NO
3
·H
2
O. The introduction of amines [imidazole (Im), 3,5-dibromopyridine (3,5-Br
2
Py), and 4-methylpyridine (4-Pic)] into the reaction mixture in a molar ratio 1 : 1 : 2 leads to the formation of CuA(HL)NO
3
·
n
H
2
O [A = Im, 3,5-Br
2
Py, 4-Pic;
n
= 0, 3] complexes. The structure of the obtained compounds was determined by X-ray structural analysis. The synthesized complexes exhibit antimicrobial, antifungal, antioxidant, and anticancer activities.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1070363221010114</doi><tpages>10</tpages></addata></record> |
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| subjects | Amines Anticancer properties Antiinfectives and antibacterials Antioxidants Biological activity Chemistry Chemistry and Materials Science Chemistry/Food Science Coordination compounds Copper Copper compounds Ethanol Fungicides Imidazole Structural analysis |
| title | Synthesis, Structure, and Biological Activity of Mixed-Ligand Amine-Containing Copper(II) Coordination Compounds with 2-(2-Hydroxybenzylidene)-N-(prop-2-en-1-yl)hydrazinecarbothioamide |
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