Ultralow Loading (Single‐Atom and Clusters) of the Pt Catalyst by Atomic Layer Deposition Using Dimethyl ((3,4‐η) N,N‐dimethyl‐3‐butene‐1‐amine‐N) Platinum (DDAP) on the High‐Surface‐Area Substrate for Hydrogen Evolution Reaction
Single‐atom Pt catalyst has seen a tremendous surge in the research community in very recent times. The minimum loading of such precious metal catalysts on high surface area substrates with effective performance toward catalyzing a reaction is indeed of great importance. Here, an alternative way is...
Gespeichert in:
Veröffentlicht in: | Advanced materials interfaces 2021-02, Vol.8 (3), p.n/a |
---|---|
Hauptverfasser: | , , , , , , , , , , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
Zusammenfassung: | Single‐atom Pt catalyst has seen a tremendous surge in the research community in very recent times. The minimum loading of such precious metal catalysts on high surface area substrates with effective performance toward catalyzing a reaction is indeed of great importance. Here, an alternative way is demonstrated to perform an ultralow loading of Pt catalyst by atomic layer deposition (ALD) using dimethyl ((3,4‐η) N,N‐dimethyl‐3‐butene‐1‐amine‐N) platinum precursor (C8H19NPt). The ultralow loading of Pt catalyst is performed on highly porous nitrogen–carbon‐powder coated carbon cloth (NC–CC) substrates by varying the number of ALD cycles (2 to 60), and their performance in electrochemical hydrogen evolution reaction (HER) is evaluated. The inductively coupled plasma‐optical emission spectrometry provides the exact mass of the Pt catalyst, whereas, the transmission electron microscopy images confirm the uniform and homogeneous dispersion of platinum single‐atoms and clusters (with an average size of |
---|---|
ISSN: | 2196-7350 2196-7350 |
DOI: | 10.1002/admi.202001508 |