Chains of cubic colloids at fluid-fluid interfaces

Inspired by recent experimental observations of spontaneous chain formation of cubic particles adsorbed at a fluid-fluid interface, we theoretically investigate whether capillary interactions can be responsible for this self-assembly process. We calculate adsorption energies, equilibrium particle orientations, and interfacial deformations, not only for a variety of contact angles but also for single cubes as well as an infinite 2D lattice of cubes at the interface. This allows us to construct a ground-state phase diagram as a function of areal density for several contact angles, and upon combining the capillary energy of a 2D lattice with a simple expression for the entropy of a 2D fluid we also construct temperature-density or size-density phase diagrams that exhibit large two-phase regions and triple points. We identify several regimes with stable chainlike structures, in line with the experimental observations. Inspired by recent experimental observations of spontaneous chain formation of cubic particles adsorbed at a fluid-fluid interface, we theoretically investigate whether capillary interactions can be responsible for this self-assembly process.