Synthesis, growth, optical, photoconductivity and specific heat properties of potassium borodicitrate (KBDC) single crystal

Nonlinear optical high-quality single crystals of potassium borodicitrate (KBDC) were grown by low-temperature solution growth slow evaporation technique. The crystal structure and quality of the grown crystal were examined by single-crystal X-ray diffraction and high-resolution X-ray diffraction an...

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Veröffentlicht in:Journal of materials science 2019-07, Vol.54 (13), p.9362-9371
Hauptverfasser: Dhatchaiyini, M. K., Rajasekar, G., Bhaskaran, A.
Format: Artikel
Sprache:eng
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Zusammenfassung:Nonlinear optical high-quality single crystals of potassium borodicitrate (KBDC) were grown by low-temperature solution growth slow evaporation technique. The crystal structure and quality of the grown crystal were examined by single-crystal X-ray diffraction and high-resolution X-ray diffraction analysis, respectively. The transmittance spectrum measured from the as-grown crystal exhibits wide range of transparency from UV to visible region. The third-order nonlinear optical properties of the grown crystal were studied using Z-scan technique. The third-order nonlinear susceptibility ( χ 3 ) of KBDC single crystal is found to be 4.1130 × 10 −9  esu. The laser-induced damage threshold for the grown crystal was measured using Nd:YAG laser. Furthermore, the photoconductivity and specific heat capacity of the crystal were measured, and the observed results are discussed in detail.
ISSN:0022-2461
1573-4803
DOI:10.1007/s10853-019-03542-4