Bell shape vs volcano shape pH dependent kinetics of the electrochemical oxidation of formic acid and formate, intrinsic kinetics or local pH shift?

Bell shape vs volcano shape pH dependent kinetics of the electrochemical oxidation of formic acid and formate, intrinsic kinetics or local pH shift?

•j-pHs diagrams for FOR in solutions with 0

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Bibliographische Detailangaben
Veröffentlicht in:Electrochimica acta 2020-12, Vol.363, p.137160, Article 137160
Hauptverfasser: Zhang, Meng-Ke, Wei, Zhen, Chen, Wei, Xu, Mian-Le, Cai, Jun, Chen, Yan-Xia
Format: Artikel
Sprache:eng
Schlagworte:
Buffers
Bulk density
Dependence
Drift
Electrochemical oxidation
Electrode/electrolyte interface
Formic acid
Formic acid oxidation
Gold
Interfacial pH change
Oxidation
pH Dependent reaction kinetics
Phosphate solution
Platinum
Reaction kinetics
Thermodynamic equilibrium
Volcanoes
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Beschreibung
Zusammenfassung:•j-pHs diagrams for FOR in solutions with 0
ISSN:0013-4686
1873-3859
DOI:10.1016/j.electacta.2020.137160