Large-size carbon-coated SnO2 composite as improved anode material for lithium ion batteries
SnO 2 microbelt coating carbon composite was fabricated via electrospinning precursor, thermal treatment, and polymer adhesion process. Primarily, the solvent of electrospinning jet quickly evaporates in a relatively high-temperature environment; intermediate microtubules simultaneously form when th...
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Veröffentlicht in: | Ionics 2020-12, Vol.26 (12), p.5879-5887 |
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Hauptverfasser: | , , , , , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | SnO
2
microbelt coating carbon composite was fabricated via electrospinning precursor, thermal treatment, and polymer adhesion process. Primarily, the solvent of electrospinning jet quickly evaporates in a relatively high-temperature environment; intermediate microtubules simultaneously form when the solute containing tin salt and binder converge on the skin of the jet; then, the microtubules collapse into flat microbelt product under the action of atmospheric pressure. Subsequently, SnO
2
microbelts can be obtained by annealing the electrospinning products. Finally, the SnO
2
@C microbelts are synthesized by dopamine polymerization and carbonization process. The SnO
2
@C microbelts present a regular strip with width ~ 1.2 μm and thickness ~ 120 nm. Because of the synergy effect of carbon coating and SnO
2
microbelt design project, the composite shows superior lithium storage of 504 mAh g
-1
after 100 cycles at 0.2 A g
-1
. The SnO
2
@C microbelts are expected to be competitive alternative anode material of next-generation LIBs.
Graphical abstract |
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ISSN: | 0947-7047 1862-0760 |
DOI: | 10.1007/s11581-020-03764-6 |