A practical strategy to access chiral α-aryloxy carboxylic acids through ion-pairing directed asymmetric hydrogenation
A series of optically active α-aryloxy carboxylic acids were obtained via Chenphos/Rh catalyzed highly efficient asymmetric hydrogenation. The proposed ion-pairing interaction between the ligand and the substrate plays a vital role in achieving high enantioselectivity.
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| Veröffentlicht in: | Organic Chemistry Frontiers 2020-12, Vol.7 (24), p.4069-4073 |
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| container_end_page | 4073 |
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| container_issue | 24 |
| container_start_page | 4069 |
| container_title | Organic Chemistry Frontiers |
| container_volume | 7 |
| creator | Yao, Lin Ma, Haixia Nie, Zhuang Nie, Huifang Zhang, Dongxu Wei, Zhao Shen, Zhanhong Chen, Weiping Jiang, Ru Zhang, Shengyong |
| description | A series of optically active α-aryloxy carboxylic acids were obtained
via
Chenphos/Rh catalyzed highly efficient asymmetric hydrogenation. The proposed ion-pairing interaction between the ligand and the substrate plays a vital role in achieving high enantioselectivity. |
| doi_str_mv | 10.1039/D0QO01205J |
| format | Article |
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| ispartof | Organic Chemistry Frontiers, 2020-12, Vol.7 (24), p.4069-4073 |
| issn | 2052-4129 2052-4110 2052-4129 2052-4110 |
| language | eng |
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| source | Royal Society Of Chemistry Journals 2008- |
| subjects | Asymmetry Carboxylic acids Crystallography Enantiomers Hydrogenation Optical activity Organic chemistry Substrates |
| title | A practical strategy to access chiral α-aryloxy carboxylic acids through ion-pairing directed asymmetric hydrogenation |
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