Preparation and Organic Solvent Adsorption of PTFE Fabric Reinforced GO/SiO2 Aerogel

The adsorption capacity of SiO2 aerogel has been greatly improved with the cross-linking of graphene and composition of PTFE fabric via sol-gel method and CO2 supercritical drying technique. The effects of MTMS/GO molar ratios are investigated, it can be found that the GO/SiO2 aerogel has a large sp...

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Veröffentlicht in:Chemistry letters 2020-11, Vol.49 (11), p.1324-1328
Hauptverfasser: Yan, Wenqian, Zhu, Kunmeng, Wu, Xiaodong, Li, Boya, Cui, Sheng, Shen, Xiaodong
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Sprache:eng
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Zusammenfassung:The adsorption capacity of SiO2 aerogel has been greatly improved with the cross-linking of graphene and composition of PTFE fabric via sol-gel method and CO2 supercritical drying technique. The effects of MTMS/GO molar ratios are investigated, it can be found that the GO/SiO2 aerogel has a large specific surface area of 551 m2/g and high pore volume of 2.2 cm3/g. Meanwhile, as an excellent adsorbent, hydrophobicity is prerequisite; the contact angle of PTFE fabric reinforced GO/SiO2 aerogel is up to 152.8°. In terms of adsorption capacity, the result shows that it can reach the value of 10.87 g/g for NMP and 9.24 g/g for cyclohexane. Furthermore, it can still retain the initial adsorption of 78.3% to 85.9% after several cycles. It is noted that the first-order kinetic model is used to prove the adsorption validity, which achieves a fitting degree over 99%.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.200414