Characterization of amorphous and crystalline ASR products formed in concrete aggregates

Amorphous and crystalline alkali silica reaction (ASR) products formed in aggregates of two different concrete mixtures exposed to the concrete prim test both at 38 °C and 60 °C have been analysed by scanning electron microscope with energy dispersive X-ray spectroscopy and by Raman microscopy. Additionally, amorphous ASR products were synthesized and analysed with Raman microscopy and 29Si nuclear magnetic resonance. Amorphous ASR products display a higher Na/K-ratio than crystalline ones. Both types of products display a structure dominated by Q3-sites (Si-tetrahedra with three bridging oxygen atoms typical for a layer structure) with a secondary amount of Q2-sites (Si-tetrahedra with two bridging oxygen atoms typical for a chain structure). Temperature in the CPT alters the structure of the crystalline ASR. While the Raman spectra of the product formed at 38 °C is identical to the one formed in concrete structures, the one of the 60 °C product corresponds to K-shlykovite.