A fluorescent supramolecular gel and its application in the ultrasensitive detection of CN by anion-π interactions

Supramolecular gels have been widely reported on account of their unique superiority and application prospects. In this work, we constructed a novel supramolecular gel ( HD-G ) by using hydroxy-naphthaldehyde decorated with naphthalimide in DMSO solution, which exhibited excellent selectivity and ultrasensitive sensing properties toward CN − (the lowest detection limit is 1.82 × 10 −10 M). The sensing mechanism of this supramolecular gel takes advantage of π-π stacking interactions and anion-π interactions, which is different from the other familiar methods. Herein, we constructed a supramolecular gelator HD based on a naphthalimide functionalized naphthaldehyde system, which could be applied in the ultrasensitive detection of CN − and the detection limit was 1.82 × 10 −10 M.