Catalysis by platinum and palladium species confined in the bulk of glass fibre materials

The results of studies on the application of silicate glass fibre materials in catalysis are summarized and analyzed. Despite the very low noble metal content, catalysts based on these materials showed exceptionally high activities and selectivities in some catalytic reactions. This is due to specificity of the glassy state, which makes it possible, first, to confine highly dispersed palladium and platinum species in the bulk of glass fibres and, second, selectively absorb polar molecules, thus excluding the undesirable reactions involving non-polar molecules. The size dependences of the complete oxidation of propane and selective hydrogenation of acetylene, the nature of the structure sensitivity of these reactions and the reaction mechanisms are discussed. Ways for improving glass fibre catalyst performance are proposed and examples of the successful application of Pt/glass fibre catalysts for purification of industrial gases from volatile organic compounds are given. The bibliography includes 175 references.