NMR spectroscopy of amino acid complexes of antimony(iii) and indium(iii) fluorides

The results of previously published NMR studies of amino acid complexes of antimony ( iii ) and indium( iii ) fluorides are critically analyzed. Correlations between the NMR data, ion mobility, and structure of the complexes in question are considered. The interpretation of the low-temperature 19 F...

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Veröffentlicht in:Russian chemical bulletin 2020-09, Vol.69 (9), p.1614-1624
Hauptverfasser: Kavun, V. Ya, Polyantsev, M. M., Zemnukhova, L. A., Udovenko, A. A.
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Sprache:eng
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Zusammenfassung:The results of previously published NMR studies of amino acid complexes of antimony ( iii ) and indium( iii ) fluorides are critically analyzed. Correlations between the NMR data, ion mobility, and structure of the complexes in question are considered. The interpretation of the low-temperature 19 F NMR spectra of amino acid complexes of antimony( iii ) fluorides is corrected and certain figures were changed for better informativity. Mechanisms of the onset of ion mobility in the studied complexes of Sb( iii ) and In( iii ) fluorides are proposed and the possibility of application of these compounds in the design of functional materials is assessed.
ISSN:1066-5285
1573-9171
DOI:10.1007/s11172-020-2945-x