Lattice‐Strain Engineering of Homogeneous NiS0.5Se0.5 Core–Shell Nanostructure as a Highly Efficient and Robust Electrocatalyst for Overall Water Splitting

Developing highly‐efficient non‐noble‐metal electrocatalysts for water splitting is crucial for the development of clean and reversible hydrogen energy. Introducing lattice strain is an effective strategy to develop efficient electrocatalysts. However, lattice strain is typically co‐created with heterostructure, vacancy, or substrate effects, which complicate the identification of the strain‐activity correlation. Herein, a series of lattice‐strained homogeneous NiSxSe1−x nanosheets@nanorods hybrids are designed and synthesized by a facile strategy. The NiS0.5Se0.5 with ≈2.7% lattice strain exhibits outstanding activity for hydrogen and oxygen evolution reaction (HER/OER), affording low overpotentials of 70 and 257 mV at 10 mA cm−2, respectively, as well as excellent long‐term durability even at a large current density of 100 mA cm−2 (300 h), significantly superior to other benchmarks and the precious metal catalysts. Experimental and theoretical calculation results reveal that the generated lattice strain decreases the metal d‐orbital overlap, leading to a narrower bandwidth and a closer d‐band center toward the Fermi level. Thus, NiS0.5Se0.5 possesses favorable H* adsorption kinetics for HER and lower energy barriers for OER. This work provides a new insight to regulate the lattice strain of advanced catalyst materials and further improve the performance of energy conversion technologies. A series of tunable lattice‐strained NiSxSe1–x core‐shell electrocatalysts are synthesized by a facile strategy. The generated lattice strain in NiS0.5Se0.5 can decrease the metal d‐orbital overlap and lead to a closer d‐band center toward the Fermi level, thus optimizing the electronic structure and reaction energy barrier for hydrogen and oxygen evolution process, enhancing the overall water splitting performance.