Base-free transfer hydrogenation of aryl-ketones, alkyl-ketones and alkenones catalyzed by an IrIIICp complex bearing a triazenide ligand functionalized with pyrazole

[Display omitted] •Iridium triazenide complex as catalysts for selective hydrogenation of α,β-unsaturated and γ,δ-unsaturated ketones.•Base free transfer hydrogenation by an iridium triazenide complex bearing a pyrazole with high yields and selectivity.•Reactivity of complexes 2 and 3 in 2-propanol...

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Veröffentlicht in:	Inorganica Chimica Acta 2020-07, Vol.507, p.119551, Article 119551
Hauptverfasser:	Medrano-Castillo, Layla J., Collazo-Flores, Miguel Á., Camarena-Díaz, Juan P., Correa-Ayala, Erick, Chávez, Daniel, Grotjahn, Douglas B., Rheingold, Arnold L., Miranda-Soto, Valentín, Parra-Hake, Miguel
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Catalytic activity Coordination compounds Hydrogen storage Ketones Ligands Metal hydrides Pyrazole Selectivity
Online-Zugang:	Volltext
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