Reagentless fabrication of a porous graphene-like electrochemical device from phenolic paper using laser-scribing

This study fabricated a portable, high-performance, and reagentless electrochemical devices using CO2 laser-scribing process, which allowed localized carbonization of a non-conductive and low-cost polymer platform, i.e., phenolic-paper. The carbonized material was extensively characterized by Raman...

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Veröffentlicht in:Carbon (New York) 2020-04, Vol.159, p.110-118
Hauptverfasser: Mendes, Letícia Francine, de Siervo, Abner, Reis de Araujo, William, Longo Cesar Paixão, Thiago Regis
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Sprache:eng
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Zusammenfassung:This study fabricated a portable, high-performance, and reagentless electrochemical devices using CO2 laser-scribing process, which allowed localized carbonization of a non-conductive and low-cost polymer platform, i.e., phenolic-paper. The carbonized material was extensively characterized by Raman spectroscopy, XPS, XRD, SEM, and electrochemical impedance spectroscopy. The carbon-based electrodes were obtained from the photothermal process induced by CO2 laser radiation and subsequently subjected to electrochemical treatment to fabricate a functional material with excellent conductivity and low charge-transfer resistance. Additionally, the laser-scribed electrodes presented a porous structure with graphene-like domains, thus indicating both potential for on-site electroanalytical applications and better performance than conventional carbon electrodes. [Display omitted]
ISSN:0008-6223
1873-3891
DOI:10.1016/j.carbon.2019.12.016