Low-temperature properties of pyrochlore Lu2Ir2O7
•A bifurcation of ZFC and FC magnetization data is observed below 140 K.•It mirrors as a broad anomaly in the temperature development of specific heat.•Short-range correlations between Ir magnetic moments, rather than long-range order of Ir sublattice.•A strong frequency dependence of ac-susceptibil...
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Veröffentlicht in: | Journal of magnetism and magnetic materials 2020-07, Vol.506, p.166793, Article 166793 |
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Sprache: | eng |
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Zusammenfassung: | •A bifurcation of ZFC and FC magnetization data is observed below 140 K.•It mirrors as a broad anomaly in the temperature development of specific heat.•Short-range correlations between Ir magnetic moments, rather than long-range order of Ir sublattice.•A strong frequency dependence of ac-susceptibility, a paradigmatic sign of a spin-glass transition.•Relatively weak electron-phonon interaction and semimetallic ground state in Lu2Ir2O7, supported by DFT calculations.
Low-temperature properties of Lu2Ir2O7 were studied by means of magnetization, ac-susceptibility and specific heat measurements. Our low-temperature measurements reveal a bifurcation of ZFC and FC magnetization data below 140 K, which is further pronounced as a broad anomaly in the temperature development of specific heat and ac-susceptibility. The anomaly can be attributed to the same physical mechanism as discussed for other A2Ir2O7 with A = magnetic rare-earth element, i.e. to short-range correlations among Ir4+ magnetic moments, rather than to a long-range order of Ir sublattice reported earlier. The ac-susceptibility data revealed a strong frequency dependence of the signal, a paradigmatic sign of a spin-glass transition. The analysis of low-temperature specific heat data brought important information on physical properties of Lu2Ir2O7, in striking agreement with our density functional theoretical (DFT) calculations, concluding relatively weak electron-phonon interaction and semimetallic ground state in Lu2Ir2O7. |
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ISSN: | 0304-8853 1873-4766 |
DOI: | 10.1016/j.jmmm.2020.166793 |