Supramolecular Aspects in Intermolecular Interaction

The proposed relations describe the pressure of saturated and superheated vapor of simple and nonpolar substances. It is shown that the noncovalent, long-range, chemical bonding forces—the Mendeleev forces—make the dominant contribution to the energy of interaction of vapor particles. The binding en...

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Veröffentlicht in:High temperature 2020-05, Vol.58 (3), p.444-447
Hauptverfasser: Neruchev, Yu. A., Bolotnikov, M. F.
Format: Artikel
Sprache:eng
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Zusammenfassung:The proposed relations describe the pressure of saturated and superheated vapor of simple and nonpolar substances. It is shown that the noncovalent, long-range, chemical bonding forces—the Mendeleev forces—make the dominant contribution to the energy of interaction of vapor particles. The binding energy is proportional to the critical temperature of the substance.
ISSN:0018-151X
1608-3156
DOI:10.1134/S0018151X20030141