A Universal Strategy for Tough Adhesion of Wet Soft Material

Achieving adhesion between hydrogels and diverse materials in a facile and universal way is challenging. Existing methods rely on special chemical or physical properties of the hydrogel and adherends, which lead to limited applicability and complicated pretreatments. A stitch‐bonding strategy is proposed here by introducing a polymer chain with versatile functional group and triggerable crosslinking property inspired by catechol chemistry. The polymer chain can stitch the hydrogel by forming a network in topological entanglement with the preexisting hydrogel network, and directly bond to the adherend surface by versatile chemical interactions. Through this, the polymer chain solution works as a universal glue for facile adhesion of hydrogels to diverse substrates like metals, glasses, elastomers, plastics, and living tissues, without requiring any chemical design or pretreatment for the hydrogel and adherends. The adhesion energy between polyacrylamide hydrogel and diverse substrates can reach 200–400 J m−2, and it can reach ≈900 J m−2 with a toughened polyacrylic acid polyacrylamide hydrogel. The mechanism of stitch‐bonding strategy is illustrated by studying various influence factors. A stitch‐bonding strategy is proposed to adhere hydrogels and diverse adherends. The adhesion is achieved by glue polymers with a versatile functional group and triggerable crosslinking property. The glue polymer forms a network in situ to topologically entangle with the hydrogel network and simultaneously bond to adherend surfaces by varied chemical interactions.