Phase Equilibria in the Li2O–Al2O3–Ni–Co–O System
— This paper presents a topological analysis of phase equilibria in the Li 2 O–Al 2 O 3 –Ni–Co–O system. Using the fragmentary experimental data available, we construct isothermal phase diagrams of the Li 2 O–Al 2 O 3 –Nc–O (Nc = Ni + Co) and Li 2 O–Al 2 O 3 –NiO 1 + x –CoO 1 + x (0 ≤ x < 1) syst...
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Veröffentlicht in: | Inorganic materials 2020-08, Vol.56 (8), p.809-814 |
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Hauptverfasser: | , |
Format: | Artikel |
Sprache: | eng |
Schlagworte: | |
Online-Zugang: | Volltext |
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This paper presents a topological analysis of phase equilibria in the Li
2
O–Al
2
O
3
–Ni–Co–O system. Using the fragmentary experimental data available, we construct isothermal phase diagrams of the Li
2
O–Al
2
O
3
–Nc–O (Nc = Ni + Co) and Li
2
O–Al
2
O
3
–NiO
1 +
x
–CoO
1 +
x
(0 ≤
x
< 1) systems. Data are presented on phase equilibria involving Li(Ni,Co,Al)O
2
(α-NaFeO
2
structure), (Li,Ni,Co,Al)Al
2
O
4
(spinel structure), (Li,Ni,Co)O (rock-salt structure), and (Li,Ni,Co)
3
O
4
(spinel structure) solid solutions, whose homogeneity regions are evaluated. |
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ISSN: | 0020-1685 1608-3172 |
DOI: | 10.1134/S0020168520070110 |