Chemically crosslinked poly(N-isopropylacrylamide-block-4-vinylpyridine) organogel with myriad applications

[Display omitted] •Chemically crosslinked organogel obtained from PNIPAM-b-P4VP diblock copolymer.•Organogel exhibited excellent dye, heavy metal adsorption and bactericidal activity.•Organogel can be recycled and reused for dye adsorption. We report the synthesis of a poly(N-isopropylacrylamide-blo...

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Veröffentlicht in:Materials letters 2020-08, Vol.272, p.127854, Article 127854
Hauptverfasser: Sridhar, Sanjeevi Prasath, John, Jacob, Kumar, Rajan, Shunmugam, Raja, Saravanan, Chandran, Joseph, Brijitta
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Sprache:eng
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Zusammenfassung:[Display omitted] •Chemically crosslinked organogel obtained from PNIPAM-b-P4VP diblock copolymer.•Organogel exhibited excellent dye, heavy metal adsorption and bactericidal activity.•Organogel can be recycled and reused for dye adsorption. We report the synthesis of a poly(N-isopropylacrylamide-block-4-vinylpyridine) (PNIPAM-b-P4VP) block copolymer and its subsequent chemical crosslinking to form a quaternized organogel. Oscillatory shear measurements are indicative of a robust elastic network in the organogel, and the critical gel point is found to be 8 wt% block copolymer with 0.8 wt% crosslinker. Interestingly, the myriad applications of the organogel across domains, including anionic dye adsorption, heavy metal removal, and antibacterial activity, suggest a new paradigm for wastewater treatment.
ISSN:0167-577X
1873-4979
DOI:10.1016/j.matlet.2020.127854