Chemically crosslinked poly(N-isopropylacrylamide-block-4-vinylpyridine) organogel with myriad applications
[Display omitted] •Chemically crosslinked organogel obtained from PNIPAM-b-P4VP diblock copolymer.•Organogel exhibited excellent dye, heavy metal adsorption and bactericidal activity.•Organogel can be recycled and reused for dye adsorption. We report the synthesis of a poly(N-isopropylacrylamide-blo...
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Veröffentlicht in: | Materials letters 2020-08, Vol.272, p.127854, Article 127854 |
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Format: | Artikel |
Sprache: | eng |
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•Chemically crosslinked organogel obtained from PNIPAM-b-P4VP diblock copolymer.•Organogel exhibited excellent dye, heavy metal adsorption and bactericidal activity.•Organogel can be recycled and reused for dye adsorption.
We report the synthesis of a poly(N-isopropylacrylamide-block-4-vinylpyridine) (PNIPAM-b-P4VP) block copolymer and its subsequent chemical crosslinking to form a quaternized organogel. Oscillatory shear measurements are indicative of a robust elastic network in the organogel, and the critical gel point is found to be 8 wt% block copolymer with 0.8 wt% crosslinker. Interestingly, the myriad applications of the organogel across domains, including anionic dye adsorption, heavy metal removal, and antibacterial activity, suggest a new paradigm for wastewater treatment. |
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ISSN: | 0167-577X 1873-4979 |
DOI: | 10.1016/j.matlet.2020.127854 |