The Solid State Structure of [TMEDAH2][B5O6(OH)4]2

The Solid State Structure of [TMEDAH2][B5O6(OH)4]2

The solid state structure of the pentaborate anion templated by a doubly protonated TMEDA cation is reported. The structure is typical of this family of ligands, featuring extensive hydrogen bonding. Spectroscopic characterisation is also reported. Graphical Abstract The structure of [TMEDAH 2 ][B 5...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Journal of chemical crystallography 2020-09, Vol.50 (3), p.171-175
Hauptverfasser: Begum, Farzana, Twamley, Brendan, Baker, Robert J.
Format: Artikel
Sprache:eng
Schlagworte:
Chemical bonds
Chemistry
Chemistry and Materials Science
Crystallography and Scattering Methods
Emitters
Hydrogen bonding
Inorganic Chemistry
Organometallic Chemistry
Original Paper
Physical Chemistry
Solid state
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The solid state structure of the pentaborate anion templated by a doubly protonated TMEDA cation is reported. The structure is typical of this family of ligands, featuring extensive hydrogen bonding. Spectroscopic characterisation is also reported. Graphical Abstract The structure of [TMEDAH 2 ][B 5 O 6 (OH) 4 ] 2 is reported and hydrogen bonding gives a ‘brickwall’ type structure. This is a blue emitter in solution.
ISSN:1074-1542
1572-8854
DOI:10.1007/s10870-019-00775-8