Structure of Complexes of Thiophosphorylthiourea Compounds with a Silver(I) Cation and Triphenylphosphine

Molecular and crystal structures of three monovalent silver complexes with chelate thiophosphorylthiourea ligands and triphenylphosphine are determined in the context of studying complexing properties of N-thiophosphorylated thioureas, thioamides, and thiosemicarbazides with the general formula RC(S...

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Veröffentlicht in:	Journal of structural chemistry 2020-06, Vol.61 (6), p.923-927
Hauptverfasser:	Litvinov, I. A., Lodochnikova, O. A., Karamov, F. A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Atomic Atomic/Molecular Structure and Spectra Cations Chemistry Chemistry and Materials Science Coordination compounds Crystal structure Inorganic Chemistry Molecular Optical and Plasma Physics Physical Chemistry Silver compounds Solid State Physics Thiosemicarbazides
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Beschreibung
Zusammenfassung:	Molecular and crystal structures of three monovalent silver complexes with chelate thiophosphorylthiourea ligands and triphenylphosphine are determined in the context of studying complexing properties of N-thiophosphorylated thioureas, thioamides, and thiosemicarbazides with the general formula RC(S)NHP(S)(O i -Pr) 2 (R = AlkNH, Alk 2 N, ArNH, PyNH, Ph, PhNHNH, NH 2 (Et)N) towards copper (I) and silver (I) cations.
ISSN:	0022-4766 1573-8779
DOI:	10.1134/S0022476620060128