Chiral Dinuclear Benzyliminobinaphthoxy‐Palladium Catalyst for Asymmetric Mannich Reaction of Aldimines and Isatin‐Derived Ketimines with Alkylmalononitriles

Chiral Dinuclear Benzyliminobinaphthoxy‐Palladium Catalyst for Asymmetric Mannich Reaction of Aldimines and Isatin‐Derived Ketimines with Alkylmalononitriles

A newly developed dinuclear bis(benzylimino)binaphthol (BIB)−Pd complex showed good catalytic activity for the Mannich reaction of aldimines and isatin‐derived ketimines with alkylmalononitriles to give the products in a highly enantioselective manner.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Advanced synthesis & catalysis 2020-08, Vol.362 (15), p.3105-3109
Hauptverfasser: Nakamura, Ayu, Kuwano, Satoru, Sun, Junchuan, Araseki, Kensuke, Ogino, Eri, Arai, Takayoshi
Format: Artikel
Sprache:eng
Schlagworte:
Asymmetric reaction
Catalytic activity
Chiral ligand
Enantiomers
Imines
Malononitrile
Mannich reaction
Metal complex
Palladium
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A newly developed dinuclear bis(benzylimino)binaphthol (BIB)−Pd complex showed good catalytic activity for the Mannich reaction of aldimines and isatin‐derived ketimines with alkylmalononitriles to give the products in a highly enantioselective manner.
ISSN:1615-4150
1615-4169
DOI:10.1002/adsc.202000447