New 11-vertex osmacarborane 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9
Hydride-containing 1,1-(PPh 3 ) 2 -1-H-3-O(CH 2 ) 4 - isonido -1,2,4-OsC 2 B 8 H 9 osmacarborane bearing a charge-compensated ligand was synthesized via a reaction of the deprotonated form of medium non-icosahedral 5,6- nido -C 2 B 8 H 12 carborane with (PPh 3 ) 3 OsCl 2 in a THF solution. The struc...
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| Veröffentlicht in: | Russian chemical bulletin 2020-06, Vol.69 (6), p.1189-1191 |
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| container_title | Russian chemical bulletin |
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| creator | Balagurova, E. V. Godovikov, I. A. Chizhevsky, I. T. |
| description | Hydride-containing 1,1-(PPh
3
)
2
-1-H-3-O(CH
2
)
4
-
isonido
-1,2,4-OsC
2
B
8
H
9
osmacarborane bearing a charge-compensated ligand was synthesized
via
a reaction of the deprotonated form of medium non-icosahedral 5,6-
nido
-C
2
B
8
H
12
carborane with (PPh
3
)
3
OsCl
2
in a THF solution. The structure of this complex was assigned using
1
H,
11
B/
11
B{
1
H}, and
31
P{
1
H} NMR spectroscopy. |
| doi_str_mv | 10.1007/s11172-020-2888-2 |
| format | Article |
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3
)
2
-1-H-3-O(CH
2
)
4
-
isonido
-1,2,4-OsC
2
B
8
H
9
osmacarborane bearing a charge-compensated ligand was synthesized
via
a reaction of the deprotonated form of medium non-icosahedral 5,6-
nido
-C
2
B
8
H
12
carborane with (PPh
3
)
3
OsCl
2
in a THF solution. The structure of this complex was assigned using
1
H,
11
B/
11
B{
1
H}, and
31
P{
1
H} NMR spectroscopy.</description><identifier>ISSN: 1066-5285</identifier><identifier>EISSN: 1573-9171</identifier><identifier>DOI: 10.1007/s11172-020-2888-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Brief Communications ; Carborane ; Chemical synthesis ; Chemistry ; Chemistry and Materials Science ; Chemistry/Food Science ; Icosahedral phase ; Inorganic Chemistry ; NMR spectroscopy ; Organic Chemistry</subject><ispartof>Russian chemical bulletin, 2020-06, Vol.69 (6), p.1189-1191</ispartof><rights>Springer Science+Business Media LLC 2020</rights><rights>Springer Science+Business Media LLC 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2312-2a9a8ab0901332afd17beb098ea5dc780b2565db249a1ff7de07e4d5cad492b33</citedby><cites>FETCH-LOGICAL-c2312-2a9a8ab0901332afd17beb098ea5dc780b2565db249a1ff7de07e4d5cad492b33</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11172-020-2888-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11172-020-2888-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Balagurova, E. V.</creatorcontrib><creatorcontrib>Godovikov, I. A.</creatorcontrib><creatorcontrib>Chizhevsky, I. T.</creatorcontrib><title>New 11-vertex osmacarborane 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9</title><title>Russian chemical bulletin</title><addtitle>Russ Chem Bull</addtitle><description>Hydride-containing 1,1-(PPh
3
)
2
-1-H-3-O(CH
2
)
4
-
isonido
-1,2,4-OsC
2
B
8
H
9
osmacarborane bearing a charge-compensated ligand was synthesized
via
a reaction of the deprotonated form of medium non-icosahedral 5,6-
nido
-C
2
B
8
H
12
carborane with (PPh
3
)
3
OsCl
2
in a THF solution. The structure of this complex was assigned using
1
H,
11
B/
11
B{
1
H}, and
31
P{
1
H} NMR spectroscopy.</description><subject>Brief Communications</subject><subject>Carborane</subject><subject>Chemical synthesis</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Chemistry/Food Science</subject><subject>Icosahedral phase</subject><subject>Inorganic Chemistry</subject><subject>NMR spectroscopy</subject><subject>Organic Chemistry</subject><issn>1066-5285</issn><issn>1573-9171</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp1kE1Lw0AQhhdRsFZ_gLeClxY6ujObdDdHDWqEYnvQ87LJbrTFJnW39ePfuyGCJ08zA8_7DjyMnSO_RM7lVUBEScCJAymlgA7YAFMpIEOJh3HnsxmkpNJjdhLCmnPeYQM2f3SfI0T4cH7nvkZt2JjK-LL1pnEjnCKMl8tXMSFAKEDAYpwXNElgFdpmZVvAKU0TWIScblSRnbKj2rwFd_Y7h-z57vYpL2C-uH_Ir-dQkUACMplRpuQZRyHI1BZl6eKpnEltJRUvKZ2ltqQkM1jX0jouXWLTytgko1KIIbvoe7e-fd-7sNPrdu-b-FJTErMksgQjhT1V-TYE72q99auN8d8aue6k6V6ajtJ0Z0NTzFCfCZFtXpz_a_4_9AMiYWjX</recordid><startdate>20200601</startdate><enddate>20200601</enddate><creator>Balagurova, E. V.</creator><creator>Godovikov, I. A.</creator><creator>Chizhevsky, I. T.</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope></search><sort><creationdate>20200601</creationdate><title>New 11-vertex osmacarborane 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9</title><author>Balagurova, E. V. ; Godovikov, I. A. ; Chizhevsky, I. T.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c2312-2a9a8ab0901332afd17beb098ea5dc780b2565db249a1ff7de07e4d5cad492b33</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Brief Communications</topic><topic>Carborane</topic><topic>Chemical synthesis</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Chemistry/Food Science</topic><topic>Icosahedral phase</topic><topic>Inorganic Chemistry</topic><topic>NMR spectroscopy</topic><topic>Organic Chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Balagurova, E. V.</creatorcontrib><creatorcontrib>Godovikov, I. A.</creatorcontrib><creatorcontrib>Chizhevsky, I. T.</creatorcontrib><collection>CrossRef</collection><jtitle>Russian chemical bulletin</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Balagurova, E. V.</au><au>Godovikov, I. A.</au><au>Chizhevsky, I. T.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New 11-vertex osmacarborane 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9</atitle><jtitle>Russian chemical bulletin</jtitle><stitle>Russ Chem Bull</stitle><date>2020-06-01</date><risdate>2020</risdate><volume>69</volume><issue>6</issue><spage>1189</spage><epage>1191</epage><pages>1189-1191</pages><issn>1066-5285</issn><eissn>1573-9171</eissn><abstract>Hydride-containing 1,1-(PPh
3
)
2
-1-H-3-O(CH
2
)
4
-
isonido
-1,2,4-OsC
2
B
8
H
9
osmacarborane bearing a charge-compensated ligand was synthesized
via
a reaction of the deprotonated form of medium non-icosahedral 5,6-
nido
-C
2
B
8
H
12
carborane with (PPh
3
)
3
OsCl
2
in a THF solution. The structure of this complex was assigned using
1
H,
11
B/
11
B{
1
H}, and
31
P{
1
H} NMR spectroscopy.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11172-020-2888-2</doi><tpages>3</tpages></addata></record> |
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| ispartof | Russian chemical bulletin, 2020-06, Vol.69 (6), p.1189-1191 |
| issn | 1066-5285 1573-9171 |
| language | eng |
| recordid | cdi_proquest_journals_2425623941 |
| source | SpringerLink Journals - AutoHoldings |
| subjects | Brief Communications Carborane Chemical synthesis Chemistry Chemistry and Materials Science Chemistry/Food Science Icosahedral phase Inorganic Chemistry NMR spectroscopy Organic Chemistry |
| title | New 11-vertex osmacarborane 1,1-(PPh3)2-1-H-3-O(CH2)4-isonido-1,2,4-OsC2B8H9 |
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