A comparison study on the substitution of Y3+−Al3+ by M2+−Si4+(M = Ba, Sr, Ca, Mg) in Y3Al5O12: Ce3+ phosphor
Y1.94MAl4SiO12:0.06Ce3+ (M = Ba, Sr, Ca, Mg) phosphors were successfully prepared through a classic solid‐state reaction method. The crystal structures, photoluminescence spectra, quantum yields, and thermal stabilities of the phosphors were investigated in detail. The results indicate that all Y1.9...
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Veröffentlicht in: | Journal of the American Ceramic Society 2020-09, Vol.103 (9), p.5111-5119 |
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Sprache: | eng |
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Zusammenfassung: | Y1.94MAl4SiO12:0.06Ce3+ (M = Ba, Sr, Ca, Mg) phosphors were successfully prepared through a classic solid‐state reaction method. The crystal structures, photoluminescence spectra, quantum yields, and thermal stabilities of the phosphors were investigated in detail. The results indicate that all Y1.94MAl4SiO12:0.06Ce3+ phosphors maintain the crystal structure of garnets. The emission peaks of Y1.94MAl4SiO12:0.06Ce3+ (M = Ba, Sr, Ca, Mg) phosphors are located at 537, 538, 554, and 565 nm, respectively. A red‐shift trend of emission peak is observed with decreasing M radius, which can be ascribed to the increase in the crystal‐field splitting in the Ce3+ 5d level owing to the co‐doping of M2+−Si4+. Under 460 nm excitation, the luminescence quantum yields and thermal stabilities of the Y1.94MAl4SiO12:0.06Ce3+ phosphors decreased with the decrease of M radius. The IQE of the Y1.94BaAl4SiO12:0.06Ce3+ phosphor is 92.89%, and the resistance to thermal quenching is improved to be 93.32% at 150°C. In addition, the color shifts of Y1.94MAl4SiO12: 0.06Ce3+ phosphors with increasing temperature are all tiny, which also demonstrates good resistance to thermal quenching of luminescence. The linear shrinkage of Y1.94MAl4SiO12:0.06Ce3+ phosphors is significantly improved compared with that of YAG: Ce3+, which is expected to generate Y1.94MAl4SiO12:0.06Ce3+ transparent/translucent ceramics and fabricate high‐powder w‐LEDs for high‐quality solid‐state lighting in the future. |
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ISSN: | 0002-7820 1551-2916 |
DOI: | 10.1111/jace.17204 |