Ball milling-derived nanostructured Li3VO4 anode with enhanced surface-confined capacitive contribution for lithium ion capacitors

To balance the kinetics gap between anode/cathode of lithium ion capacitors (LICs), we developed a straightforward ball milling method to tune the electrochemical performance of Li 3 VO 4 (LVO) particles. After the mechanical crushing, the particle size of the pristine LVO with a densely bulky struc...

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Veröffentlicht in:Ionics 2020-08, Vol.26 (8), p.4129-4140
Hauptverfasser: Zhang, Miaoxin, Zhang, Xin, Liu, Zexin, Peng, Huifen, Wang, Gongkai
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Sprache:eng
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Zusammenfassung:To balance the kinetics gap between anode/cathode of lithium ion capacitors (LICs), we developed a straightforward ball milling method to tune the electrochemical performance of Li 3 VO 4 (LVO) particles. After the mechanical crushing, the particle size of the pristine LVO with a densely bulky structure is reduced significantly; furthermore, a partial transition from V 5+ to V 4+ may induce the oxygen vacancy, resulting into the shortened Li + diffusion path and low diffusion barrier. More active sites are exposed, and the long-range ordering of the structure is disturbed, leading to a fast Li + transport on the surface or subsurface. The calculated capacitive contribution ratio achieves 49.6% at the lowest scan rate. The LICs deliver high energy and power densities (max. 108.5 Wh kg −1 at 114.5 W kg −1 , 1180 W kg −1 at 21 Wh kg −1 ), revealing the efficiency of ball milling to facilitate the surface-induced capacitive contribution toward high-performance LICs.
ISSN:0947-7047
1862-0760
DOI:10.1007/s11581-020-03537-1