Nonenzymatic amperometric sensor for hydrogen peroxide released from living cancer cells based on hierarchical NiCo2O4-CoNiO2 hybrids embedded in partially reduced graphene oxide
The synthesis of hierarchical NiCo 2 O 4 -CoNiO 2 hybrids embedded in partially reduced graphene oxide (represented by NiCo 2 O 4 /CoNiO 2 @pPRGO) is described. They were derived from ultrathin CoNi-based zeolitic imidazolate framework (CoNi-ZIF) nanosheets vertically grew on three-dimensional (3D)...
Gespeichert in:
| Veröffentlicht in: | Mikrochimica acta (1966) 2020-08, Vol.187 (8), Article 436 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | |
|---|---|
| container_issue | 8 |
| container_start_page | |
| container_title | Mikrochimica acta (1966) |
| container_volume | 187 |
| creator | Wang, Minghua Wang, Changbao Liu, Yongkang Hu, Bin He, Linghao Ma, Yashen Zhang, Zhihong Cui, Bingbing Du, Miao |
| description | The synthesis of hierarchical NiCo
2
O
4
-CoNiO
2
hybrids embedded in partially reduced graphene oxide (represented by NiCo
2
O
4
/CoNiO
2
@pPRGO) is described. They were derived from ultrathin CoNi-based zeolitic imidazolate framework (CoNi-ZIF) nanosheets vertically grew on three-dimensional (3D) pRGO networks by pyrolysis at different temperatures (300, 600, and 900 °C) in N
2
atmosphere. Transmission electron microscopy, X-ray diffraction, and X-ray photoemission spectroscopy measurements showed that the metal coordination centers (Co or Ni) were transferred into NiCo
2
O
4
spinel and CoNiO
2
nanostructures, along with a small number of metallic states of Co and Ni. In view of good electrochemical conductivity and large specific surface area of pRGO, good catalytic activity of Co- and Ni-contained NPs, and homogeneous distribution of NPs within the pRGO network, the NiCo
2
O
4
/CoNiO
2
@pRGO
600
nanohybrid calcined at 600 °C displayed superior electrocatalytic activity toward hydrogen peroxide (H
2
O
2
) reduction. A glassy carbon electrode modified with NiCo
2
O
4
/CoNiO
2
@pRGO
600
was used for determination of H
2
O
2
by amperometry at an applied potential of − 0.4 V vs. Ag/AgCl. The nonenzymatic amperometric sensor exhibited high sensitivity and low detection limit (0.41 μM) within a wide working range (5 μM–3 mM and 3–12 mM) toward H
2
O
2
, as well as good selectivity, reproducibility, and long-term stability. Benefiting from the good biocompatibility and remarkable analytical performances of NiCo
2
O
4
/CoNiO
2
@pRGO
600
, the assay was used to determine real-time H
2
O
2
released from living cancer cells.
Graphical abstract |
| doi_str_mv | 10.1007/s00604-020-04419-z |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_journals_2422066790</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2422066790</sourcerecordid><originalsourceid>FETCH-LOGICAL-c267z-2e609c2ffd4c4105a8fb9e3430bcf33a6484073a5d50f3942d879b64ea16bc913</originalsourceid><addsrcrecordid>eNp9kU-rEzEUxYMoWJ9-AVcB16M3f5rpLKWoT3i0G12HTHLT5jGT1JtWbD-Wn9C8VnDnIoTc-zvnQA5jbwW8FwD9hwpgQHcgoQOtxdBdnrGF0Mp0S-jVc7YAkKZTppcv2ataHwFEb6ResN-bkjFfzrM7Js_dfEAqMx6pPSrmWojHdvbnQGWHmT-tf6WAnHBCVzHw2Hg-pZ8p77h32SNxj9NU-Xhdl8z3CcmR3yfvJr5J6yK3uluXTdrKZjxSCpXjPGIIjU8tw9ExuWk6t5Bw8m24I3fYY0Z-zX7NXkQ3VXzz975j3z9_-ra-7x62X76uPz50Xpr-0kk0MHgZY9BeC1i6VRwHVFrB6KNSzuiVbn_jlmEJUQ1ahlU_jEajE2b0g1B37N3N90Dlxwnr0T6WE-UWaaWWEozpB2iUvFGeSq2E0R4ozY7OVoB96sbeurGtG3vtxl6aSN1EtcF5h_TP-j-qP7-Ylgw</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2422066790</pqid></control><display><type>article</type><title>Nonenzymatic amperometric sensor for hydrogen peroxide released from living cancer cells based on hierarchical NiCo2O4-CoNiO2 hybrids embedded in partially reduced graphene oxide</title><source>SpringerLink Journals</source><creator>Wang, Minghua ; Wang, Changbao ; Liu, Yongkang ; Hu, Bin ; He, Linghao ; Ma, Yashen ; Zhang, Zhihong ; Cui, Bingbing ; Du, Miao</creator><creatorcontrib>Wang, Minghua ; Wang, Changbao ; Liu, Yongkang ; Hu, Bin ; He, Linghao ; Ma, Yashen ; Zhang, Zhihong ; Cui, Bingbing ; Du, Miao</creatorcontrib><description>The synthesis of hierarchical NiCo
2
O
4
-CoNiO
2
hybrids embedded in partially reduced graphene oxide (represented by NiCo
2
O
4
/CoNiO
2
@pPRGO) is described. They were derived from ultrathin CoNi-based zeolitic imidazolate framework (CoNi-ZIF) nanosheets vertically grew on three-dimensional (3D) pRGO networks by pyrolysis at different temperatures (300, 600, and 900 °C) in N
2
atmosphere. Transmission electron microscopy, X-ray diffraction, and X-ray photoemission spectroscopy measurements showed that the metal coordination centers (Co or Ni) were transferred into NiCo
2
O
4
spinel and CoNiO
2
nanostructures, along with a small number of metallic states of Co and Ni. In view of good electrochemical conductivity and large specific surface area of pRGO, good catalytic activity of Co- and Ni-contained NPs, and homogeneous distribution of NPs within the pRGO network, the NiCo
2
O
4
/CoNiO
2
@pRGO
600
nanohybrid calcined at 600 °C displayed superior electrocatalytic activity toward hydrogen peroxide (H
2
O
2
) reduction. A glassy carbon electrode modified with NiCo
2
O
4
/CoNiO
2
@pRGO
600
was used for determination of H
2
O
2
by amperometry at an applied potential of − 0.4 V vs. Ag/AgCl. The nonenzymatic amperometric sensor exhibited high sensitivity and low detection limit (0.41 μM) within a wide working range (5 μM–3 mM and 3–12 mM) toward H
2
O
2
, as well as good selectivity, reproducibility, and long-term stability. Benefiting from the good biocompatibility and remarkable analytical performances of NiCo
2
O
4
/CoNiO
2
@pRGO
600
, the assay was used to determine real-time H
2
O
2
released from living cancer cells.
Graphical abstract</description><identifier>ISSN: 0026-3672</identifier><identifier>EISSN: 1436-5073</identifier><identifier>DOI: 10.1007/s00604-020-04419-z</identifier><language>eng</language><publisher>Vienna: Springer Vienna</publisher><subject>Analytical Chemistry ; Biocompatibility ; Cancer ; Catalytic activity ; Characterization and Evaluation of Materials ; Chemistry ; Chemistry and Materials Science ; Electrical measurement ; Glassy carbon ; Graphene ; Graphical representations ; Hydrogen peroxide ; Intermetallic compounds ; Metal-organic frameworks ; Microengineering ; Nanochemistry ; Nanotechnology ; Nickel compounds ; Original Paper ; Photoelectric emission ; Pyrolysis ; Selectivity ; Silver chloride ; Stability analysis ; Zeolites</subject><ispartof>Mikrochimica acta (1966), 2020-08, Vol.187 (8), Article 436</ispartof><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2020</rights><rights>Springer-Verlag GmbH Austria, part of Springer Nature 2020.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c267z-2e609c2ffd4c4105a8fb9e3430bcf33a6484073a5d50f3942d879b64ea16bc913</citedby><cites>FETCH-LOGICAL-c267z-2e609c2ffd4c4105a8fb9e3430bcf33a6484073a5d50f3942d879b64ea16bc913</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s00604-020-04419-z$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s00604-020-04419-z$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Wang, Minghua</creatorcontrib><creatorcontrib>Wang, Changbao</creatorcontrib><creatorcontrib>Liu, Yongkang</creatorcontrib><creatorcontrib>Hu, Bin</creatorcontrib><creatorcontrib>He, Linghao</creatorcontrib><creatorcontrib>Ma, Yashen</creatorcontrib><creatorcontrib>Zhang, Zhihong</creatorcontrib><creatorcontrib>Cui, Bingbing</creatorcontrib><creatorcontrib>Du, Miao</creatorcontrib><title>Nonenzymatic amperometric sensor for hydrogen peroxide released from living cancer cells based on hierarchical NiCo2O4-CoNiO2 hybrids embedded in partially reduced graphene oxide</title><title>Mikrochimica acta (1966)</title><addtitle>Microchim Acta</addtitle><description>The synthesis of hierarchical NiCo
2
O
4
-CoNiO
2
hybrids embedded in partially reduced graphene oxide (represented by NiCo
2
O
4
/CoNiO
2
@pPRGO) is described. They were derived from ultrathin CoNi-based zeolitic imidazolate framework (CoNi-ZIF) nanosheets vertically grew on three-dimensional (3D) pRGO networks by pyrolysis at different temperatures (300, 600, and 900 °C) in N
2
atmosphere. Transmission electron microscopy, X-ray diffraction, and X-ray photoemission spectroscopy measurements showed that the metal coordination centers (Co or Ni) were transferred into NiCo
2
O
4
spinel and CoNiO
2
nanostructures, along with a small number of metallic states of Co and Ni. In view of good electrochemical conductivity and large specific surface area of pRGO, good catalytic activity of Co- and Ni-contained NPs, and homogeneous distribution of NPs within the pRGO network, the NiCo
2
O
4
/CoNiO
2
@pRGO
600
nanohybrid calcined at 600 °C displayed superior electrocatalytic activity toward hydrogen peroxide (H
2
O
2
) reduction. A glassy carbon electrode modified with NiCo
2
O
4
/CoNiO
2
@pRGO
600
was used for determination of H
2
O
2
by amperometry at an applied potential of − 0.4 V vs. Ag/AgCl. The nonenzymatic amperometric sensor exhibited high sensitivity and low detection limit (0.41 μM) within a wide working range (5 μM–3 mM and 3–12 mM) toward H
2
O
2
, as well as good selectivity, reproducibility, and long-term stability. Benefiting from the good biocompatibility and remarkable analytical performances of NiCo
2
O
4
/CoNiO
2
@pRGO
600
, the assay was used to determine real-time H
2
O
2
released from living cancer cells.
Graphical abstract</description><subject>Analytical Chemistry</subject><subject>Biocompatibility</subject><subject>Cancer</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Electrical measurement</subject><subject>Glassy carbon</subject><subject>Graphene</subject><subject>Graphical representations</subject><subject>Hydrogen peroxide</subject><subject>Intermetallic compounds</subject><subject>Metal-organic frameworks</subject><subject>Microengineering</subject><subject>Nanochemistry</subject><subject>Nanotechnology</subject><subject>Nickel compounds</subject><subject>Original Paper</subject><subject>Photoelectric emission</subject><subject>Pyrolysis</subject><subject>Selectivity</subject><subject>Silver chloride</subject><subject>Stability analysis</subject><subject>Zeolites</subject><issn>0026-3672</issn><issn>1436-5073</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kU-rEzEUxYMoWJ9-AVcB16M3f5rpLKWoT3i0G12HTHLT5jGT1JtWbD-Wn9C8VnDnIoTc-zvnQA5jbwW8FwD9hwpgQHcgoQOtxdBdnrGF0Mp0S-jVc7YAkKZTppcv2ataHwFEb6ResN-bkjFfzrM7Js_dfEAqMx6pPSrmWojHdvbnQGWHmT-tf6WAnHBCVzHw2Hg-pZ8p77h32SNxj9NU-Xhdl8z3CcmR3yfvJr5J6yK3uluXTdrKZjxSCpXjPGIIjU8tw9ExuWk6t5Bw8m24I3fYY0Z-zX7NXkQ3VXzz975j3z9_-ra-7x62X76uPz50Xpr-0kk0MHgZY9BeC1i6VRwHVFrB6KNSzuiVbn_jlmEJUQ1ahlU_jEajE2b0g1B37N3N90Dlxwnr0T6WE-UWaaWWEozpB2iUvFGeSq2E0R4ozY7OVoB96sbeurGtG3vtxl6aSN1EtcF5h_TP-j-qP7-Ylgw</recordid><startdate>20200801</startdate><enddate>20200801</enddate><creator>Wang, Minghua</creator><creator>Wang, Changbao</creator><creator>Liu, Yongkang</creator><creator>Hu, Bin</creator><creator>He, Linghao</creator><creator>Ma, Yashen</creator><creator>Zhang, Zhihong</creator><creator>Cui, Bingbing</creator><creator>Du, Miao</creator><general>Springer Vienna</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>K9.</scope></search><sort><creationdate>20200801</creationdate><title>Nonenzymatic amperometric sensor for hydrogen peroxide released from living cancer cells based on hierarchical NiCo2O4-CoNiO2 hybrids embedded in partially reduced graphene oxide</title><author>Wang, Minghua ; Wang, Changbao ; Liu, Yongkang ; Hu, Bin ; He, Linghao ; Ma, Yashen ; Zhang, Zhihong ; Cui, Bingbing ; Du, Miao</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c267z-2e609c2ffd4c4105a8fb9e3430bcf33a6484073a5d50f3942d879b64ea16bc913</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Analytical Chemistry</topic><topic>Biocompatibility</topic><topic>Cancer</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Electrical measurement</topic><topic>Glassy carbon</topic><topic>Graphene</topic><topic>Graphical representations</topic><topic>Hydrogen peroxide</topic><topic>Intermetallic compounds</topic><topic>Metal-organic frameworks</topic><topic>Microengineering</topic><topic>Nanochemistry</topic><topic>Nanotechnology</topic><topic>Nickel compounds</topic><topic>Original Paper</topic><topic>Photoelectric emission</topic><topic>Pyrolysis</topic><topic>Selectivity</topic><topic>Silver chloride</topic><topic>Stability analysis</topic><topic>Zeolites</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Minghua</creatorcontrib><creatorcontrib>Wang, Changbao</creatorcontrib><creatorcontrib>Liu, Yongkang</creatorcontrib><creatorcontrib>Hu, Bin</creatorcontrib><creatorcontrib>He, Linghao</creatorcontrib><creatorcontrib>Ma, Yashen</creatorcontrib><creatorcontrib>Zhang, Zhihong</creatorcontrib><creatorcontrib>Cui, Bingbing</creatorcontrib><creatorcontrib>Du, Miao</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><jtitle>Mikrochimica acta (1966)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Minghua</au><au>Wang, Changbao</au><au>Liu, Yongkang</au><au>Hu, Bin</au><au>He, Linghao</au><au>Ma, Yashen</au><au>Zhang, Zhihong</au><au>Cui, Bingbing</au><au>Du, Miao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Nonenzymatic amperometric sensor for hydrogen peroxide released from living cancer cells based on hierarchical NiCo2O4-CoNiO2 hybrids embedded in partially reduced graphene oxide</atitle><jtitle>Mikrochimica acta (1966)</jtitle><stitle>Microchim Acta</stitle><date>2020-08-01</date><risdate>2020</risdate><volume>187</volume><issue>8</issue><artnum>436</artnum><issn>0026-3672</issn><eissn>1436-5073</eissn><abstract>The synthesis of hierarchical NiCo
2
O
4
-CoNiO
2
hybrids embedded in partially reduced graphene oxide (represented by NiCo
2
O
4
/CoNiO
2
@pPRGO) is described. They were derived from ultrathin CoNi-based zeolitic imidazolate framework (CoNi-ZIF) nanosheets vertically grew on three-dimensional (3D) pRGO networks by pyrolysis at different temperatures (300, 600, and 900 °C) in N
2
atmosphere. Transmission electron microscopy, X-ray diffraction, and X-ray photoemission spectroscopy measurements showed that the metal coordination centers (Co or Ni) were transferred into NiCo
2
O
4
spinel and CoNiO
2
nanostructures, along with a small number of metallic states of Co and Ni. In view of good electrochemical conductivity and large specific surface area of pRGO, good catalytic activity of Co- and Ni-contained NPs, and homogeneous distribution of NPs within the pRGO network, the NiCo
2
O
4
/CoNiO
2
@pRGO
600
nanohybrid calcined at 600 °C displayed superior electrocatalytic activity toward hydrogen peroxide (H
2
O
2
) reduction. A glassy carbon electrode modified with NiCo
2
O
4
/CoNiO
2
@pRGO
600
was used for determination of H
2
O
2
by amperometry at an applied potential of − 0.4 V vs. Ag/AgCl. The nonenzymatic amperometric sensor exhibited high sensitivity and low detection limit (0.41 μM) within a wide working range (5 μM–3 mM and 3–12 mM) toward H
2
O
2
, as well as good selectivity, reproducibility, and long-term stability. Benefiting from the good biocompatibility and remarkable analytical performances of NiCo
2
O
4
/CoNiO
2
@pRGO
600
, the assay was used to determine real-time H
2
O
2
released from living cancer cells.
Graphical abstract</abstract><cop>Vienna</cop><pub>Springer Vienna</pub><doi>10.1007/s00604-020-04419-z</doi></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0026-3672 |
| ispartof | Mikrochimica acta (1966), 2020-08, Vol.187 (8), Article 436 |
| issn | 0026-3672 1436-5073 |
| language | eng |
| recordid | cdi_proquest_journals_2422066790 |
| source | SpringerLink Journals |
| subjects | Analytical Chemistry Biocompatibility Cancer Catalytic activity Characterization and Evaluation of Materials Chemistry Chemistry and Materials Science Electrical measurement Glassy carbon Graphene Graphical representations Hydrogen peroxide Intermetallic compounds Metal-organic frameworks Microengineering Nanochemistry Nanotechnology Nickel compounds Original Paper Photoelectric emission Pyrolysis Selectivity Silver chloride Stability analysis Zeolites |
| title | Nonenzymatic amperometric sensor for hydrogen peroxide released from living cancer cells based on hierarchical NiCo2O4-CoNiO2 hybrids embedded in partially reduced graphene oxide |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-26T01%3A39%3A12IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Nonenzymatic%20amperometric%20sensor%20for%20hydrogen%20peroxide%20released%20from%20living%20cancer%20cells%20based%20on%20hierarchical%20NiCo2O4-CoNiO2%20hybrids%20embedded%20in%20partially%20reduced%20graphene%20oxide&rft.jtitle=Mikrochimica%20acta%20(1966)&rft.au=Wang,%20Minghua&rft.date=2020-08-01&rft.volume=187&rft.issue=8&rft.artnum=436&rft.issn=0026-3672&rft.eissn=1436-5073&rft_id=info:doi/10.1007/s00604-020-04419-z&rft_dat=%3Cproquest_cross%3E2422066790%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=2422066790&rft_id=info:pmid/&rfr_iscdi=true |