Domino Decarboxylation–CO2 Fixation – a Route toward Cyclic Carbonates and Oxazolidinones (Microreview)

Domino Decarboxylation–CO2 Fixation – a Route toward Cyclic Carbonates and Oxazolidinones (Microreview)

Transition metal-catalyzed transformations of carboxylic acids and their derivatives via decarboxylation–CO 2 fixation cascade contribute to an important class of indirect chemical utilization of CO 2 and allow obtaining heterocycles. Recent examples of palladium- and copper-catalyzed domino decarbo...

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Veröffentlicht in:Chemistry of heterocyclic compounds (New York, N.Y. 1965) N.Y. 1965), 2020-05, Vol.56 (5), p.506-508
1. Verfasser: Feng, Huangdi
Format: Artikel
Sprache:eng
Schlagworte:
Carbon dioxide
Carbonates
Carboxylic acids
Cascade chemical reactions
Chemical reactions
Chemistry
Chemistry and Materials Science
Decarboxylation
Fixation
Organic Chemistry
Palladium
Pharmacy
Transition metals
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Zusammenfassung:Transition metal-catalyzed transformations of carboxylic acids and their derivatives via decarboxylation–CO 2 fixation cascade contribute to an important class of indirect chemical utilization of CO 2 and allow obtaining heterocycles. Recent examples of palladium- and copper-catalyzed domino decarboxylation–CO 2 fixation reactions are summarized in two main categories: generation of cyclic carbonates and oxazolidinones.
ISSN:0009-3122
1573-8353
DOI:10.1007/s10593-020-02689-2