One-Pot Facile Synthesis of La0.5Sr0.5CoO3/C by Sol-Microwave Method and Its Electrocatalytic Activity for Oxygen Evolution Reaction

The La 0.5 Sr 0.5 CoO 3 /C was synthesized by sol-microwave process, which has globular particle with size range of 15–25 nm and distributed evenly. The electrode prepared with this catalyst has a current density of 141 mA·cm −2 at 0.7 V (vs. Hg/HgO) in an alkaline medium (6 mol·L −1 KOH). La 0.5 Sr...

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Veröffentlicht in:Catalysis letters 2019-05, Vol.149 (5), p.1211-1215
Hauptverfasser: Zhang, Zejie, Zhou, Debi, Wu, Xuewen, Qin, Mulan, Yu, Huazhang, Wen, Meisheng
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container_end_page 1215
container_issue 5
container_start_page 1211
container_title Catalysis letters
container_volume 149
creator Zhang, Zejie
Zhou, Debi
Wu, Xuewen
Qin, Mulan
Yu, Huazhang
Wen, Meisheng
description The La 0.5 Sr 0.5 CoO 3 /C was synthesized by sol-microwave process, which has globular particle with size range of 15–25 nm and distributed evenly. The electrode prepared with this catalyst has a current density of 141 mA·cm −2 at 0.7 V (vs. Hg/HgO) in an alkaline medium (6 mol·L −1 KOH). La 0.5 Sr 0.5 CoO 3 /C has excellent catalytic performance for oxygen evolution, which is superior to RuO 2 /C catalyst and can replace noble metal catalytic materials. Graphical Abstract The polarization curves of oxygen evolution for La 0.5 Sr 0.5 CoO 3 /C electrode and RuO 2 (20%)/C electrode are shown. At 0.7 V (vs. Hg/HgO), the oxygen evolution current density is 141 and 135 mA·cm −2 , respectively. The results show that perovskite-type oxide La 0.5 Sr 0.5 CoO 3 /C prepared by sol-microwave method has better catalytic performance than RuO 2 (20%)/C.
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The electrode prepared with this catalyst has a current density of 141 mA·cm −2 at 0.7 V (vs. Hg/HgO) in an alkaline medium (6 mol·L −1 KOH). La 0.5 Sr 0.5 CoO 3 /C has excellent catalytic performance for oxygen evolution, which is superior to RuO 2 /C catalyst and can replace noble metal catalytic materials. Graphical Abstract The polarization curves of oxygen evolution for La 0.5 Sr 0.5 CoO 3 /C electrode and RuO 2 (20%)/C electrode are shown. At 0.7 V (vs. Hg/HgO), the oxygen evolution current density is 141 and 135 mA·cm −2 , respectively. The results show that perovskite-type oxide La 0.5 Sr 0.5 CoO 3 /C prepared by sol-microwave method has better catalytic performance than RuO 2 (20%)/C.</description><identifier>ISSN: 1011-372X</identifier><identifier>EISSN: 1572-879X</identifier><identifier>DOI: 10.1007/s10562-019-02726-6</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Current density ; Electrode polarization ; Electrodes ; Industrial Chemistry/Chemical Engineering ; Noble metals ; Organometallic Chemistry ; Oxygen evolution reactions ; Perovskites ; Physical Chemistry ; Ruthenium oxide</subject><ispartof>Catalysis letters, 2019-05, Vol.149 (5), p.1211-1215</ispartof><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019</rights><rights>Springer Science+Business Media, LLC, part of Springer Nature 2019.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c330t-b1d1471e3a96eaf7277cc84b970fee286227a91df96e14ab7019cac2c568c2d23</citedby><cites>FETCH-LOGICAL-c330t-b1d1471e3a96eaf7277cc84b970fee286227a91df96e14ab7019cac2c568c2d23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10562-019-02726-6$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10562-019-02726-6$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Zhang, Zejie</creatorcontrib><creatorcontrib>Zhou, Debi</creatorcontrib><creatorcontrib>Wu, Xuewen</creatorcontrib><creatorcontrib>Qin, Mulan</creatorcontrib><creatorcontrib>Yu, Huazhang</creatorcontrib><creatorcontrib>Wen, Meisheng</creatorcontrib><title>One-Pot Facile Synthesis of La0.5Sr0.5CoO3/C by Sol-Microwave Method and Its Electrocatalytic Activity for Oxygen Evolution Reaction</title><title>Catalysis letters</title><addtitle>Catal Lett</addtitle><description>The La 0.5 Sr 0.5 CoO 3 /C was synthesized by sol-microwave process, which has globular particle with size range of 15–25 nm and distributed evenly. 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The electrode prepared with this catalyst has a current density of 141 mA·cm −2 at 0.7 V (vs. Hg/HgO) in an alkaline medium (6 mol·L −1 KOH). La 0.5 Sr 0.5 CoO 3 /C has excellent catalytic performance for oxygen evolution, which is superior to RuO 2 /C catalyst and can replace noble metal catalytic materials. Graphical Abstract The polarization curves of oxygen evolution for La 0.5 Sr 0.5 CoO 3 /C electrode and RuO 2 (20%)/C electrode are shown. At 0.7 V (vs. Hg/HgO), the oxygen evolution current density is 141 and 135 mA·cm −2 , respectively. The results show that perovskite-type oxide La 0.5 Sr 0.5 CoO 3 /C prepared by sol-microwave method has better catalytic performance than RuO 2 (20%)/C.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10562-019-02726-6</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record>
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subjects Catalysis
Catalysts
Chemistry
Chemistry and Materials Science
Current density
Electrode polarization
Electrodes
Industrial Chemistry/Chemical Engineering
Noble metals
Organometallic Chemistry
Oxygen evolution reactions
Perovskites
Physical Chemistry
Ruthenium oxide
title One-Pot Facile Synthesis of La0.5Sr0.5CoO3/C by Sol-Microwave Method and Its Electrocatalytic Activity for Oxygen Evolution Reaction
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