One-Pot Facile Synthesis of La0.5Sr0.5CoO3/C by Sol-Microwave Method and Its Electrocatalytic Activity for Oxygen Evolution Reaction

The La 0.5 Sr 0.5 CoO 3 /C was synthesized by sol-microwave process, which has globular particle with size range of 15–25 nm and distributed evenly. The electrode prepared with this catalyst has a current density of 141 mA·cm −2 at 0.7 V (vs. Hg/HgO) in an alkaline medium (6 mol·L −1 KOH). La 0.5 Sr...

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Veröffentlicht in:Catalysis letters 2019-05, Vol.149 (5), p.1211-1215
Hauptverfasser: Zhang, Zejie, Zhou, Debi, Wu, Xuewen, Qin, Mulan, Yu, Huazhang, Wen, Meisheng
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Sprache:eng
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Zusammenfassung:The La 0.5 Sr 0.5 CoO 3 /C was synthesized by sol-microwave process, which has globular particle with size range of 15–25 nm and distributed evenly. The electrode prepared with this catalyst has a current density of 141 mA·cm −2 at 0.7 V (vs. Hg/HgO) in an alkaline medium (6 mol·L −1 KOH). La 0.5 Sr 0.5 CoO 3 /C has excellent catalytic performance for oxygen evolution, which is superior to RuO 2 /C catalyst and can replace noble metal catalytic materials. Graphical Abstract The polarization curves of oxygen evolution for La 0.5 Sr 0.5 CoO 3 /C electrode and RuO 2 (20%)/C electrode are shown. At 0.7 V (vs. Hg/HgO), the oxygen evolution current density is 141 and 135 mA·cm −2 , respectively. The results show that perovskite-type oxide La 0.5 Sr 0.5 CoO 3 /C prepared by sol-microwave method has better catalytic performance than RuO 2 (20%)/C.
ISSN:1011-372X
1572-879X
DOI:10.1007/s10562-019-02726-6