Benzylic C−H Functionalisation by [Et3SiH+KOtBu] leads to Radical Rearrangements in o‐tolyl Aryl Ethers, Amines and Sulfides

Reaction of Et3SiH+KOtBu with diaryl ethers, sulfides and amines that feature an ortho alkyl group leads to rearrangement products. The rearrangements arise from formation of benzyl radicals, likely formed through hydrogen atom ion by triethylsilyl radicals. The rearrangements involve cyclisation of...

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Veröffentlicht in:	Advanced synthesis & catalysis 2020-05, Vol.362 (11), p.2260-2267
Hauptverfasser:	Arokianathar, Jude N., Kolodziejczak, Krystian, Bugden, Frances E., Clark, Kenneth F., Tuttle, Tell, Murphy, John A.
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Aromatic compounds Diaryl ethers KOtBu radical Radicals silane Sulfides Truce-Smiles rearrangement
Online-Zugang:	Volltext
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