Resorcinol-Formaldehyde Resins for Cesium Removal from Solutions Produced after Processing Spent Ion-Exchangers

A series of resorcinol-formaldehyde resins (RFR) has been prepared and studied in terms of Cs-137 uptake efficiency from solutions (0.75М NaOH-2.25M NaNO3) intended for processing spent ion-exchangers. Sample synthesized at molar ratio of resorcinol to formaldehyde of 1.8:2.2 and solidified at 210 °...

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Veröffentlicht in:Key engineering materials 2020-05, Vol.842, p.107-114
Hauptverfasser: Tutov, Mikhail V., Tokar', Eduard, Palamarchuk, Marina, Egorin, Andrei, Matskevich, Anna
Format: Artikel
Sprache:eng
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Zusammenfassung:A series of resorcinol-formaldehyde resins (RFR) has been prepared and studied in terms of Cs-137 uptake efficiency from solutions (0.75М NaOH-2.25M NaNO3) intended for processing spent ion-exchangers. Sample synthesized at molar ratio of resorcinol to formaldehyde of 1.8:2.2 and solidified at 210 °C (sample RFR-3-1-210) has shown the best sorption-selective performance and chemical stability. Implementing RFR in dynamic sorption scheme enables to reduce its decay due to short contact time. In dynamic conditions, after feeding 1000 bed volumes of the solution, RFR 3-1-210 maintains its sorption properties after 6 sorption-desorption cycles.
ISSN:1013-9826
1662-9795
1662-9795
DOI:10.4028/www.scientific.net/KEM.842.107