Volatile components of deep-fried soybean oil as indicator indices of lipid oxidation and quality degradation
The present study investigated the lipid oxidation degree of soybean oil during regularly discontinuous 40 h-deep-frying process. Electron spin resonance (ESR) spectroscopy technique was applied to identify and quantify the formed radicals, along with evaluation of physicochemical parameters includi...
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Veröffentlicht in: | European food research & technology 2020-06, Vol.246 (6), p.1183-1192 |
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Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | The present study investigated the lipid oxidation degree of soybean oil during regularly discontinuous 40 h-deep-frying process. Electron spin resonance (ESR) spectroscopy technique was applied to identify and quantify the formed radicals, along with evaluation of physicochemical parameters including acid value (AV), peroxide value (PV),
p
-anisidine value (
p
-AnV), polar compounds (PC), fatty acid composition and volatile profile. Results showed the AV,
p
-AnV, PC and free radical of frying oil samples increased significantly with the increasing frying time. The results of fatty acids showed that unsaturated fatty acid such as C18:1 and C18:2 decreased by 19.98% and 14.58%, respectively, with prolonged frying time, while the content of C16:1,
trans
C18:1 and C18:2 increased by 20.38%, 425% and 42.86%, respectively, when compared to the fresh oil samples. In contrast, the content of saturated fatty acid had little change. In total, 37 volatile compounds were detected revealing a complex aroma profile of frying soybean oil, composed of 15 aldehydes, 8 alcohols, 4 ketones, 4 acids, 5 alkanes and 1 furan. Principal component analysis and hierarchical clustering analysis indicated that hexanal, heptanal, (
E
)-2-hexenal, octanal, (
E
)-2-heptenal, nonanal, (
E
)-2-octenal, undecanal, (
E,E
)-2,4-heptadienal, (
E
)-2-decenal, 2-undecenal, (
E,E
)-2,4-decadienal, 1-pentanol, 2,2-dimethyl-3-hexanol, (
Z
)-2-dodecenol, 1-octen-3-ol, pentanoic acid, octanoic acid, nonanoic acid and 2-pentyl-furan may be potential markers for evaluating lipid oxidation of frying soybean oil. |
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ISSN: | 1438-2377 1438-2385 |
DOI: | 10.1007/s00217-020-03475-2 |